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Synthesis, Crystal Structure, and Characterizations of tetra(N-Benzoylmethyl-benzimidazole)dibromide cadmium(II) Complex: CdBr2(C7H5N2CH2COPh)4

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Abstract

The structure of CdBr2(C7H5N2CH2COPh)4 has been determined by X-ray crystallography. It crystallizes in the tetragonal system, space group P4/n, with lattice parameters a = 14.904(3) Å, b = 14.904(3) Å, c = 11.817(2) Å, and Z = 2. The crystal structure consists of monomeric molecules of [CdBr2(C7H5N2CH2COPh)4] with distorted octahedron geometry for the CdBr2N4 chromophore. It is also characterized by elemental analysis, IR spectrum, electronic spectrum, and thermogravimetric-differential scanning calorimetry (TG-DSC).

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Authors and Affiliations

  1. New Materials and Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao, Shandong, 266042, People's Republic of China

    Fangfang Jian, Pingping Sun & Hailian Xiao

  2. Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing, Jiangsu, 210094, People's Republic of China

    Pusu Zhao

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  1. Fangfang Jian
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  2. Pingping Sun
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  3. Hailian Xiao
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  4. Pusu Zhao
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Correspondence to Fangfang Jian.

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Jian, F., Sun, P., Xiao, H. et al. Synthesis, Crystal Structure, and Characterizations of tetra(N-Benzoylmethyl-benzimidazole)dibromide cadmium(II) Complex: CdBr2(C7H5N2CH2COPh)4. Struct Chem 16, 561–565 (2005). https://doi.org/10.1007/s11224-005-8621-9

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