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Synthesis, Characterization, and Crystal Engineering of [NiII(1,2-Diaminocyclohexane)3](N3)Cl: Three-Dimensional Framework by Hexafurcated N–H ⋅s Cl− Hydrogen Bonds

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Abstract

Synthesis, characterization, and crystal engineering of a tris chelate compound, [NiIIL3](N3)Cl (1), (L = diequatorial trans-1,2-diaminocyclohexane) have been described. The compound crystallizes in the cubic P4332 space group with a = 13.859(12) Å and Z = 4. In this structure, the azide anion is highly disordered. Each chloride in 1 interacts with six amine hydrogens and is surrounded by three mononuclear cations, each of which, in turn, are linked with three chlorides to form a three-dimensional channel network. This is the first report of hexafurcated (acceptor) N–H ⋅s Cl− hydrogen bonds in metalloorganic systems and the first report of the three-dimensional framework resulted basically due to the multifurcated acceptor nature of the halide anion.

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Authors and Affiliations

  1. Department of Chemistry, University of Calcutta, 92 A. P. C. Ray Road, Kolkata, 700 009, India

    Malabika Nayak & Sasankasekhar Mohanta

  2. Department of Chemistry, Ramananda College, Bishnupur, Bankura, West Bengal, India

    Parimal Kundu

  3. School of Chemistry, The University Whiteknights, Reading, RG6 6AD, United Kingdom

    Michael G. B. Drew

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  1. Malabika Nayak
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  2. Parimal Kundu
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  4. Sasankasekhar Mohanta
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Correspondence to Sasankasekhar Mohanta.

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Nayak, M., Kundu, P., Drew, M.G.B. et al. Synthesis, Characterization, and Crystal Engineering of [NiII(1,2-Diaminocyclohexane)3](N3)Cl: Three-Dimensional Framework by Hexafurcated N–H ⋅s Cl− Hydrogen Bonds. Struct Chem 16, 629–633 (2005). https://doi.org/10.1007/s11224-005-8251-2

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