A method of analytical description of one of the most complex problems in the study of high symmetry quantum-mechanical objects, namely, tetrahedral splittings, is considered. Results are presented that allow tetrahedral splittings of the vibrational states of A1 and A2 symmetries for polyad N ≤ 4 to be determined in an analytical form.
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 34–38, October, 2017.
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Raspopova, N.I., Sklyarova, E.A., Aslapovskaya, Y.S. et al. Determining the Parameters of Tetrahedral Splittings in the A1- and A2-Type States of Molecules with Spherical Symmetry (T d or О h ). Russ Phys J 60, 1684–1689 (2018). https://doi.org/10.1007/s11182-018-1269-x
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DOI: https://doi.org/10.1007/s11182-018-1269-x