Abstract
The method of high-resolution pulsed optical spectroscopy is used to investigate the spectral-kinetic characteristics of explosive emission of pentaerythritol tetranitrate crystal excited by a pulsed electron beam (0.25 MeV, 35 ns, and 15 J/cm2). It is established that emission with the spectrum comprising three components with maxima at 3.1, 2.4, and 1.5 eV is initiated in the edge of the excitation pulse. Moreover, transformation of the emission spectrum is observed directly within the time over which the excitation pulse acts followed by the emission decay; however, emission develops again on the subnanosecond scale; moreover, its spectrum contains only the 1.5-eV band, which appears to be an indicator of the self-sustaining chemical reaction of explosive decomposition. The 3.1-and 2.4-eV bands are identified as emissions of an exciton and a primary NO 2* radiative defect, and the 1.5-eV band is probably connected with the NO 3 radical.
Similar content being viewed by others
References
V. N. Shvaiko, A. G. Krechetov, B. P. Aduev, et al., Zh. Tekh. Fiz., 75, No. 6, 59–62 (2005).
B. P. Aduev, E. D. Aluker, G. M. Belokurov, et al., Preexplosive Phenomena in Heavy Metal Azides [in Russian], Khimmash Central Energy Press, Moscow (2002).
Z. A. Dreger, Yu. A. Gruzdkov, et al., J. Phys. Chem., B106(2), 247–256 (2002).
G. H. Myers, D. M. Silver, and F. Kaufman, J. Chem. Phys., 44, No. 2, 718–723 (1966).
R. Piers and A. Geidon, Identification of Molecular Spectra [Russian translation], Inostrannaya Literatura, Moscow (1949).
D. I. Vaisburd, ed., High-energy Solid-State Electronics [in Russian], Nauka, Novosibirsk (1982).
A. A. Borisov, ed., Detonation and Explosives [in Russian], Mir, Moscow (1981).
E. D. Aluker, D. J. Lusis, and S. A. Chernov, Electronic Excitations and Radioluminescence of Alkali-Halide Crystals [in Russian], Znanie, Riga (1979).
M. M. Kuklja, E. V. Stefanovich, and A. B. Kunz, J. Chem. Phys., 112, No. 7, 3417–3423 (2000).
R. T. Morrison and R. N. Boyd, Organic Chemistry, Allyn and Bacon, Boston (1987).
Author information
Authors and Affiliations
Additional information
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 3–9, February, 2007.
Rights and permissions
About this article
Cite this article
Aduev, B.P., Belokurov, G.M., Grechin, C.C. et al. Investigation of early stages of explosive pentaerythritol tetranitrate crystal decomposition initiated by pulsed electron beams. Russ Phys J 50, 99–106 (2007). https://doi.org/10.1007/s11182-007-0014-7
Issue Date:
DOI: https://doi.org/10.1007/s11182-007-0014-7