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Reactions of phenylenedioxytrihalophosphoranes with arylacetylenes: VII. Reaction of 2,2,2-trichloro-4-fluoro-1,3,2λ5-benzodioxaphosphole with phenylacetylene

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Abstract

2,2,2-Trichloro-4-fluoro-1,3,2λ5-benzodioxaphosphole reacts with phenylacetylene to give 2,7-dichloro-5-fluoro-4-phenyl-2H-1,2λ5-benzoxaphosphinine 2-oxide. Hydrolysis of the latter leads to opening of the oxaphosphinine ring with formation of (E)-2-(4-chloro-2-fluoro-6-hydroxyphenyl)-2-phenylethenylphosphonic acid.

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REFERENCES

  1. Mironov, V.F., Shtyrlina, A.A., Varaksina, E.N., Gubaidullin, A.T., Azancheev, N.M., Dobrynin, A.B., Litvinov, I.A., Musin, R.Z., and Konovalov, A.I., Zh. Obshch. Khim., 2004, vol. 74, p. 1953.

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  2. Mironov, V.F., Konovalov, A.I., Litvinov, I.A., Gubaidullin, A.T., Petrov, R.R., Shtyrlina, A.A., Zyablikova, T.A., Musin, R.Z., Azancheev, N.M., and Il’yasov, A.V., Russ. J. Gen. Chem., 1998, vol. 68, p. 1414.

    CAS  Google Scholar 

  3. Mironov, V.F., Shtyrlina, A.A., Gubaidullin, A.T., Bogdanov, A.V., Litvinov, I.A., Azancheev, N.M., Latypov, Sh.K., Musin, R.Z., and Efremov, Yu.Ya., Izv. Ross. Akad. Nauk, Ser. Khim., 2004, no. 1, p. 186.

  4. Mironov, V.F., Litvinov, I.A., Shtyrlina, A.A., Gubaidullin, A.T., Petrov, R.R., Konovalov, A.I., Azancheev, N.M., and Musin, R.Z., Russ. J. Gen. Chem., 2000, vol. 70, p. 1046.

    CAS  Google Scholar 

  5. Mironov, V.F., Baronova, T.A., Gubaidullin, A.T., Musin, R.Z., Azancheev, N.M., Latypov, Sh.K., Dobrynin, A.B., Alekseev, F.F., Litvinov, I.A., and Konovalov, A.I., Dokl. Ross. Akad. Nauk, 2002, vol. 385, p. 196.

    Google Scholar 

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, Tatarstan, 420088, Russia

    V. F. Mironov, A. A. Shtyrlina, E. N. Varaksina, Yu. Ya. Efremov & A. I. Konovalov

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  1. V. F. Mironov
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  2. A. A. Shtyrlina
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  3. E. N. Varaksina
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  4. Yu. Ya. Efremov
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  5. A. I. Konovalov
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Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 12, 2004, pp. 1846–1851.

Original Russian Text Copyright © 2004 by Mironov, Shtyrlina, Varaksina, Efremov, Konovalov.

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Mironov, V.F., Shtyrlina, A.A., Varaksina, E.N. et al. Reactions of phenylenedioxytrihalophosphoranes with arylacetylenes: VII. Reaction of 2,2,2-trichloro-4-fluoro-1,3,2λ5-benzodioxaphosphole with phenylacetylene. Russ J Org Chem 40, 1798–1803 (2004). https://doi.org/10.1007/s11178-005-0102-5

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  • DOI: https://doi.org/10.1007/s11178-005-0102-5

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