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Solvent Effect on the Rate of Dimerization of Cyclopentadiene

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Abstract

The rate of dimerization of cyclopentadiene and some other cycloaddition reactions is determined by electrophilic solvation of the substrate with some contribution of other solvation factors, primarily nonspecific solvation. The corresponding dependence is described by multiparameter equations.

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REFERENCES

  1. Shuikin, N.I. and Naryshkina, T.I., Zh. Fiz. Khim., 1957, vol. 31, no.2, p. 493.

    CAS  Google Scholar 

  2. Coster, G. and Pfeil, E., Chem. Ber., 1968, vol. 101, no.12, p. 4248.

    Google Scholar 

  3. Reichardt, Ch., Solvents and Solvent Effects in Organic Chemistry, Weinheim: Wiley, 2003, pp. 178, 284, 294.

    Google Scholar 

  4. Koppel, I.A. and Palm, V.A., Advances in Linear Free Energy Relationships, Chapman, N.B. and Shorter, J., Eds., London: Plenum, 1972, p. 203.

    Google Scholar 

  5. Makitra, R.G. and Pristanskii, R.E., Zh. Obshch. Khim., 2004, vol. 74, no.12, p. 1948.

    Google Scholar 

  6. Makitra, R.G., Pirig, Ya.N., and Kivelyuk, R.B., Available from VINITI, Moscow, 1986, no. 628–V86.

  7. Abboud, J.L.M. and Notario, R., Pure Appl. Chem., 1999, vol. 71, no.4, p. 645.

    CAS  Google Scholar 

  8. Recommendations for Reporting the Results of Correlation Analysis in Chemistry using Regression Analysis, Quant. Struct. Act. Relat., 1985, vol. 4, no.1, p. 29.

  9. Wong, K.F. and Eckert, C.A., Ind. Eng. Chem. Process Des. Devel., 1963, vol. 8, no.4, p. 568.

    Google Scholar 

  10. Pytela, O., Collect. Czech. Chem. Commun., 1988, vol. 53, no.7, p. 1333.

    Article  CAS  Google Scholar 

  11. Denisov, E.T., Konstanty skorosti gomoliticheskikh zhidkofaznykh reaktsii (Rate Constants of Homolytic Liquid-Phase Reactions), Moscow: Nauka, 1971.

    Google Scholar 

  12. Corsico Coda, A., Desimoni, G., Ferrari, E., Righetti, P.P., and Tacconi, G., Tetrahedron, 1984, vol. 40, no.9, p. 1611.

    Article  CAS  Google Scholar 

  13. Piatek, A., Chapuis, Ch., and Jurczak, J., J. Phys. Org. Chem., 2003, vol. 16, no.10, p. 700.

    CAS  Google Scholar 

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Authors and Affiliations

  1. L'vovskaya Politekhnika National University, L'viv, Ukraine

    N. M. Karpyak, G. A. Marshalok & I. I. Yatchishin

  2. Institute of Geology and Geochemistry of Fossil Fuels, National Academy of Sciences of Ukraine, L'viv, Ukraine

    R. G. Makitra & O. Ya. Pal'chikova

Authors
  1. N. M. Karpyak
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  2. R. G. Makitra
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  3. G. A. Marshalok
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  4. O. Ya. Pal'chikova
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  5. I. I. Yatchishin
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 11, 2005, pp. 1794–1798.

Original Russian Text Copyright © 2005 by Karpyak, Makitra, Marshalok, Pal'chikova, Yatchishin.

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Karpyak, N.M., Makitra, R.G., Marshalok, G.A. et al. Solvent Effect on the Rate of Dimerization of Cyclopentadiene. Russ J Gen Chem 75, 1712–1716 (2005). https://doi.org/10.1007/s11176-005-0497-2

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  • DOI: https://doi.org/10.1007/s11176-005-0497-2

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