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Adamantylazoles: X. Reactions of 1,2,4-Triazole-3-thione with 1-Adamantanol in Acid Solutions

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Abstract

1,2,4-Triazole-3-thione reacts with 1-adamantanol in concentrated sulfuric acid to form 1-(1-adamantyl)-1,2,4-triazole-3-thione, which transforms into 1-(1-adamantyl)-3-(1-adamantyl)sulfanyl-1,2,4-triazole or is oxidized with atmospheric oxygen dissolved in sulfuric acid into 3,3′-disulfanediylbis[1-(1-adamantyl)- 1,2,4-triazole]. 3-(1-Adamantyl)sulfanyl-1,2,4-triazole was prepared by adamantylation of 1,2,4-triazole-3-thione in a mixture of phosphoric and acetic acid (weight ratio 4 : 1).

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, Technical University, St. Petersburg, Russia

    A. D. Amandurdyeva, V. V. Saraev & E. L. Golod

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. N. Polyakova

Authors
  1. A. D. Amandurdyeva
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  2. V. V. Saraev
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  3. I. N. Polyakova
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  4. E. L. Golod
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Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 9, 2005, pp. 1548–1552.

Original Russian Text Copyright © 2005 by Amandurdyeva, Saraev, Polyakova, Golod.

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Amandurdyeva, A.D., Saraev, V.V., Polyakova, I.N. et al. Adamantylazoles: X. Reactions of 1,2,4-Triazole-3-thione with 1-Adamantanol in Acid Solutions. Russ J Gen Chem 75, 1475–1479 (2005). https://doi.org/10.1007/s11176-005-0449-x

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  • DOI: https://doi.org/10.1007/s11176-005-0449-x

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