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N,N′-Bis(trimethylsilylmethyl)thiocarbamide and N,N′-Bis(trimethylsilylmethyl)-λ6-thiocarbamide S,S-Dioxide

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Abstract

N,N′-Bis(trimethylsilylmethyl)-λ6-thiocarbamide S,S-dioxide was synthesized by oxidation of N,N′-bis(trimethylsilylmethyl)thiocarbamide with hydrogen peroxide. The synthesized dioxide is a less active reducing agent than previously studied S,S-dioxides of organosilicon thiocarbamides in which the silicon atom is separated from the thiocarbamide fragment by a -CH2CH2CH2- bridge.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    N. N. Vlasova, O. Yu. Grigor’eva & M. G. Voronkov

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  1. N. N. Vlasova
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  2. O. Yu. Grigor’eva
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  3. M. G. Voronkov
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Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 6, 2005, pp. 912–914.

Original Russian Text Copyright © 2005 by Vlasova, Grigor’eva, Voronkov.

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Vlasova, N.N., Grigor’eva, O.Y. & Voronkov, M.G. N,N′-Bis(trimethylsilylmethyl)thiocarbamide and N,N′-Bis(trimethylsilylmethyl)-λ6-thiocarbamide S,S-Dioxide. Russ J Gen Chem 75, 860–861 (2005). https://doi.org/10.1007/s11176-005-0334-7

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  • DOI: https://doi.org/10.1007/s11176-005-0334-7

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