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Mechanochemical Synthesis of Poly(germanium and tin organosiloxanes)

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Abstract

The mechanochemical reaction of polyphenylsiloxane with tin and germanium oxides gives rise to soluble tin and germanium phenylsiloxanes. Effect of the nature of the oxide and of the starting reagent ratio on the yield and composition of metal phenylsiloxanes was studied. The reaction products were studied by IR spectroscopy and X-ray phase analysis.

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REFERENCES

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Authors and Affiliations

  1. Far-East State University, Vladivostok, Russia

    A. A. Kapustina, N. P. Shapkin, E. B. Ivanova & A. A. Lyakhina

Authors
  1. A. A. Kapustina
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  2. N. P. Shapkin
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  3. E. B. Ivanova
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  4. A. A. Lyakhina
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 4, 2005, pp. 610–613.

Original Russian Text Copyright © 2005 by Kapustina, Shapkin, Ivanova, Lyakhina.

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Kapustina, A.A., Shapkin, N.P., Ivanova, E.B. et al. Mechanochemical Synthesis of Poly(germanium and tin organosiloxanes). Russ J Gen Chem 75, 571–574 (2005). https://doi.org/10.1007/s11176-005-0273-3

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  • DOI: https://doi.org/10.1007/s11176-005-0273-3

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