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Electrochemical Methods for Studying Transport Properties and the Type of Ionic Conduction in Solid Electrolytes Based on CaPr2S4 and Ca(Ba)Sm2S4

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Abstract

The theoretical feasibility of sulfide ion transport in phases based on MeLn2S4 (Me = Ca, Ba; Ln = Sm, Pr) is considered. Regions of solid solutions on the basis of ternary compounds are determined. A systematic investigation of phases is performed with the application of a variety of electrochemical methods, specifically, the conductimetry, emf in chemical concentration cells with and without transport, and Tubandt methods.

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REFERENCES

  1. Ivanov-Shits, A.K. and Murin, I.V., Ionika tverdogo tela (Solid State Ionics), St. Petersburg: Sankt-Peterburg. Gos. Univ., 2000, vol. 1.

    Google Scholar 

  2. Kalinina, L.A., Cand. Sci. Dissertation, Moscow: Moscow State Univ., 1975.

  3. Kalinina, L.A., Shirokova, G.I., Lyalina, M.Yu, and Murin, I.V., in Elektrodika tverdotel’nykh sistem (Electrodics in Solid State Systems), Sverdlovsk: Ural. Div. Ross. Akad. Nauk, 1991, p. 18.

    Google Scholar 

  4. Kalinina, L.A., Shyrokova, G.I., Murin, I.V., and Lyalina, M.Yu., 4th Int. Symp. on Systems with Fast Ionic Transport, Warsaw, 1994, p. 77.

  5. Kalinina, L.A., Shirokova, G.I., Murin, I.V., Ushakova, Yu.N., Fominykh, E.G., and Lyalina, M.Yu., Zh. Prikl. Khim., 2000, vol. 73, p. 1324.

    Google Scholar 

  6. Ushakova, Yu.N., Kalinina, L.A., Murin, I.V., and Shirokova, G.I., Vestn. SPbGU, Ser. 4., 1997, issue 4, p. 64.

  7. Fominykh, E.G., Kalinina, L.A., Murin, I.V., and Shirokova, G.I., Vestn. SPbGU, Ser. 4., 1997, p. 71.

  8. Guseinov, R.M. and Kukoz, F.I., Elektronnye protsessy v tverdykh elektrolitakh (Electrode Processes in Solid Electrolytes), Rostov-on-Don: Rostov. Gos. Univ., 1986.

    Google Scholar 

  9. Chebotin, V.N. and Obrosov, V.P., Tr. Inst. Elektrokhim. Ural. Otd. Akad. Nauk SSSR, 1972, issue 18, p. 151.

  10. Obrosov, V.P. and Karpachev, S.V., Tr. Inst. Elektrokhim. Ural. Otd. Akad. Nauk SSSR, 1970, issue 14, p. 119.

  11. Gerasimov, Ya.I., Kutsenok, I.B., and Geiderikh, V.A., Dokl. Akad. Nauk SSSR, 1979, vol. 244, p. 633.

    Google Scholar 

  12. Kalinina, L.A., Murin, I.V., Lyalina, M.Yu., and Shirokova, G.I., Elektrokhimiya, 1995, vol. 31, p. 634.

    Google Scholar 

  13. Tubandt, C., Zn. Handbook: Exp. Phys., Leipzig, 1932, vol. 1, p. 383.

    Google Scholar 

  14. Chebotin, V.N. and Perfil’ev, M.V., Elektrokhimiya tverdykh elektrolitov (The Electrochemistry of Solid Electrolytes), Moscow: Khimiya, 1978.

    Google Scholar 

  15. Takahashi, T. and Yamamato, O., Electrochim. Acta, 1966, vol. 11, p. 779.

    Article  Google Scholar 

  16. Ivanov-Shits, A.K. and Gurevich, Yu.Ya., Elektrokhimiya, 1980, vol. 16, p. 3.

    Google Scholar 

  17. Mobius, H.H., Z. Chem., 1962, no. 2, p. 100.

  18. Pal’guev, S.F., Neiumin, A.D., and Strekalovskii, V.N., Tr. Inst. Elektrokhim. Ural. Otd. Akad. Nauk SSSR, 1966, issue 9, p. 149.

  19. Kalinina, L.A., Lyalina, M.Yu., Murin, I.V., and Shirokova, G.I., Available from VINITI, 1998, Moscow, no. 122-v98.

  20. Chebotin, V.N. and Obrosov, V.P., Tr. Inst. Elektrokhim. Ural. Otd. Akad. Nauk SSSR, 1972, issue 18, p. 151.

  21. Tret’yakov, Yu.D., Khimiya nestekhiometricheskikh okislov (The Chemistry of Nonstoichiometric Oxides), Moscow: Mosk. Gos. Univ., 1974.

    Google Scholar 

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Authors and Affiliations

  1. Vyatka State University, ul. Moskovskaya 36, Kirov, 610000, Russia

    Yu. N. Ushakova, L. A. Kalinina, E. G. Fominykh & I. S. Yurlov

  2. St. Petersburg State University, Universitetskii pr. 26, St. Petergof, 198504, Russia

    I. V. Murin

Authors
  1. Yu. N. Ushakova
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  2. L. A. Kalinina
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  3. E. G. Fominykh
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  4. I. S. Yurlov
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  5. I. V. Murin
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Correspondence to L. A. Kalinina.

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__________

Translated from Elektrokhimiya, Vol. 41, No. 6, 2005, pp. 707–713.

Original Russian Text Copyright © 2005 by Ushakova, Kalinina, Fominykh, Yurlov, Murin.

Published on the basis of a report delivered at the VII Meeting on Fundamental Problems in Solid-State Ionics (Chernogolovka-2004).

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Ushakova, Y.N., Kalinina, L.A., Fominykh, E.G. et al. Electrochemical Methods for Studying Transport Properties and the Type of Ionic Conduction in Solid Electrolytes Based on CaPr2S4 and Ca(Ba)Sm2S4 . Russ J Electrochem 41, 625–631 (2005). https://doi.org/10.1007/s11175-005-0115-y

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  • DOI: https://doi.org/10.1007/s11175-005-0115-y

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