Skip to main content
SpringerLink
Log in

Liquid-Crystalline and Orientation Properties of Lanthanide Complexes with β-Enaminoketone

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

A series of liquid-crystalline lanthanide complexes with 1-(4-dodecyloxyphenyl)-3-octadecylamino-2-propene-1-one (HL), which is substituted β-enaminoketone, with the composition Ln(HL)3(NO3)3 (Ln = La, Nd, Gd, Tb, Dy, Ho, and Er) is synthesized. For the most part of the synthesized complexes, the magnetic susceptibility anisotropy (Δχmin) is shown to be one to two orders higher than Δχ of the “classical” organic liquid crystals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Metallomesogens: Synthesis, Properties, and Applications, Serrano, J.L., Ed., New York: VCH, 1996.

    Google Scholar 

  2. Donnio, B, Guillon, D, Deschenaux, R, and Bruce, D.W, in Comprehensive Coordination Chemistry II, McCleverty, J.A. and Meyer, Th.J., Eds., Oxford: Elsevier, 2004, p. 357.

    Google Scholar 

  3. Hudson, S.A. and Maitlis, P.M., Chem. Rev., 1993, vol. 93, no.3, p. 861.

    Article  Google Scholar 

  4. Galyametdinov, Yu.G., Atanassopoulo, M., Khaaze, V., and Ovchinnikov, I.V., Koord. Khim., 1995, vol. 21, no.9, p. 751.

    Google Scholar 

  5. Ovchinnikov, I.V., Galyametdinov, Yu.G., and Prosvirin, A.V., Izv. Ross. Akad. Nauk, Ser. Khim., 1995, no. 4, p. 787.

  6. Galyametdinov, Yu., Athanassopoulou, M.A., Griesar, K., et al., Chem. Mater., 1996, vol. 8, no.4, p. 922.

    Article  Google Scholar 

  7. Driesen, K. and Binnemans, K., Liq. Cryst., 2004, vol. 31, no.4, p. 601.

    Article  Google Scholar 

  8. Ovchinnikov, I.V. and Galyametdinov, Yu.G., Ross. Khim. Zh., 2001, vol. 45, no.3, p. 74.

    Google Scholar 

  9. Garnovskii, A.D., Panyushkin, V.T., and Gritsenko, T.V., Koord. Khim, 1981, vol. 7, no.4, p. 483.

    Google Scholar 

  10. Blek, D. and Khartshorn, A., Usp. Khim., 1975, vol. 44, no.2, p. 160.

    Google Scholar 

  11. Garnovskii, A.D. and Vasil'chenko, I.S., Usp. Khim., 2002, vol. 71, no.11, p. 1064.

    Google Scholar 

  12. Demus, D., Goodby, J., Gray, G.W., et al., Handbook of Liquid Crystals, New York: VCH, 1998.

    Google Scholar 

  13. Galyametdinov, Yu.G., Kharitonova, O.A., Kadkin, O.N., and Ovchinnikov, I.V., Izv. Ross. Akad. Nauk, Ser. Khim., 1994, no. 9, p. 1685.

  14. Kharitonova, O.A., Prosvirin, A.V., Galyametdinov, Yu.G., and Ovchinnikov, I.V., Izv. Ross. Akad. Nauk, Ser. Khim., 1996, no. 9, p. 2331.

  15. Goncharov, V.A. and Turanov, A.N., Prib. Tekh. Eksp., 1998, no. 4, p. 145.

  16. Turanova, O.A., Galyametdinov, Yu.G., and Ovchinnikov, I.V., Izv.Ross. Akad. Nauk, Ser. Khim., 2001, no. 5, p. 771.

  17. Vul'fson, S.G., Molekulyarnaya magnetokhimiya (Molecular Magnetochemistry), Moscow: Nauka, 1991.

    Google Scholar 

  18. Turanov, A., Ovchinnikov, I., Galyametdinov, Yu., and Bruce, D., Liq. Cryst., 2001, vol. 28, no.6, p. 845.

    Article  Google Scholar 

  19. Gorller-Walrand, C and Binnemans, K., Handbook on the Physics and Chemistry of Rare Earths, Gschneidner, K.A. Jr. and Eyring, L., Eds., Amsterdam: NH, 1996, vol. 23, p. 121.

    Google Scholar 

  20. Binnemans, K., Galyametdinov, Yu.G., Haase, W., et al., J. Am. Chem. Soc., 2000, vol. 122, no.18, p. 4335.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Zavoisky Physicotechnical Institute, Kazan Scientific Center, Russian Academy of Sciences, Sibirsky trakt 10/7, Kazan 29, Tatarstan, 420029, Russia

    O. A. Turanova, A. N. Turanov & I. V. Ovchinnikov

  2. Kazan State Technological University, ul. Karla Marksa 68, Kazan, Tatarstan, 420015, Russia

    Yu. G. Galyametdinov

Authors
  1. O. A. Turanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. N. Turanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Ovchinnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. G. Galyametdinov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 10, 2005, pp. 796–800.

Original Russian Text Copyright © 2005 by Turanova, Turanov, Ovchinnikov, Galyametdinov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Turanova, O.A., Turanov, A.N., Ovchinnikov, I.V. et al. Liquid-Crystalline and Orientation Properties of Lanthanide Complexes with β-Enaminoketone. Russ J Coord Chem 31, 757–760 (2005). https://doi.org/10.1007/s11173-005-0165-4

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11173-005-0165-4

Keywords

Search

Navigation