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New Solvate Polymorphs of Lanthanide Trisacetylacetonates: Crystal Structures of [Ln(acac)3(H2O)2] · Solv (Ln = Eu, Dy; Solv = Thf, H2O + EtOH, MeOH)

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Abstract

Solvate polymorphs of [Dy(acac)3(H2O)2] · Thf, [Ln(acac)3(H2O)2] · H2O · EtOH (Ln = Eu, Dy) and [Dy(acac)3(H2O)2] · 1.5MeOH, which belongs to a new structural type, are isolated as single crystals. The structures of the prepared compounds are determined by X-ray crystallography, and the effect of solvate molecules on their crystal structures is discussed.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. B. Ilyukhin, A. V. Gavrikov, Zh. V. Dobrokhotova & V. M. Novotortsev

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  1. A. B. Ilyukhin
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  2. A. V. Gavrikov
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  3. Zh. V. Dobrokhotova
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  4. V. M. Novotortsev
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Correspondence to A. B. Ilyukhin.

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Original Russian Text © A.B. Ilyukhin, A.V. Gavrikov, Zh.V. Dobrokhotova, V.M. Novotortsev, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 9, pp. 1161–1166.

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Ilyukhin, A.B., Gavrikov, A.V., Dobrokhotova, Z.V. et al. New Solvate Polymorphs of Lanthanide Trisacetylacetonates: Crystal Structures of [Ln(acac)3(H2O)2] · Solv (Ln = Eu, Dy; Solv = Thf, H2O + EtOH, MeOH). Russ. J. Inorg. Chem. 63, 1186–1191 (2018). https://doi.org/10.1134/S003602361809005X

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  • DOI: https://doi.org/10.1134/S003602361809005X

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