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Crystal Structure of Sodium Perchloratotriacetatoneptunate(V) Monohydrate Na3NpO2(OOCCH3)3ClO4 · H2O

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Abstract

The crystal structure of Na3NpO2(OOCCH3)3ClO4 · H2O was studied by single-crystal X-ray diffraction method. The structure is composed of the complex anions NpO2(OOCCH3)3]2−, perchlorate anions, Na cations, and water molecules. The oxygen environment of Np(V) is a hexagonal bipyramid whose equatorial plane is formed by the oxygen atoms of three acetate ions. In addition to the acetate anions, the structure contains the perchlorate ion whose oxygen atoms, except for one, are included in the coordination environment of Na+ cations.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117915, Russia

    I. A. Charushnikova & A. M. Fedoseev

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, GSP-1, 117813, Russia

    Z. A. Starikova

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  1. I. A. Charushnikova
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  2. A. M. Fedoseev
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  3. Z. A. Starikova
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Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 8, 2005, pp. 636–640.

Original Russian Text Copyright © 2005 by Charushnikova, Fedoseev, Starikova.

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Charushnikova, I.A., Fedoseev, A.M. & Starikova, Z.A. Crystal Structure of Sodium Perchloratotriacetatoneptunate(V) Monohydrate Na3NpO2(OOCCH3)3ClO4 · H2O. Russ J Coord Chem 31, 603–607 (2005). https://doi.org/10.1007/s11173-005-0143-x

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  • DOI: https://doi.org/10.1007/s11173-005-0143-x

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