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Complexation between N-allylmorpholinium derivatives and copper(I) halides. Synthesis and crystal structure of π-complex {[C4H8ONH(C3H5)]+}2[Cu2Cl4]2−

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Abstract

Copper(I) π-complex {[C4H8ONH(C3H5)]+}2[Cu2Cl4]2− (I) was obtained by ac electrochemical synthesis from N-allylmorpholine hydrochloride and copper(II) chloride in ethanol and structurally characterized. In structure I, copper and chlorine atoms form unique noncentrosymmetric Cu2Cl 2−4 fragments. Both crystallographically independent N-allylmorpholinium cations are involved in the π-interaction and are coordinated by the copper atom through the C=C bond of the allyl group. The trigonal pyramidal environment of the Cu(1) atom is composed of three chlorine atoms and the C=C bond, while the Cu(2) atom coordinates two chlorine atoms and the C=C bond forming a planar triangle. The extremely strong N-C⋯Cl hydrogen bond (H⋯Cl 2.2 Å) prevents the Cl(1) atom from acting as a bridge and favors the formation of fragments Cu2Cl 2−4 .

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Authors and Affiliations

  1. Georg-August University, Tammannstrasse 2, D-37077, Göttingen, Germany

    E. A. Goreshnik

  2. Franko National University, Kirilla i Mefodiya 6, Lviv, 79005, Ukraine

    V. N. Davydov & M. G. Mys’kiv

Authors
  1. E. A. Goreshnik
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  2. V. N. Davydov
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  3. M. G. Mys’kiv
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Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 4, 2005, pp. 306–310.

Original Russian Text Copyright © 2005 by Goreshnik, Davydov, Mys’kiv.

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Goreshnik, E.A., Davydov, V.N. & Mys’kiv, M.G. Complexation between N-allylmorpholinium derivatives and copper(I) halides. Synthesis and crystal structure of π-complex {[C4H8ONH(C3H5)]+}2[Cu2Cl4]2− . Russ J Coord Chem 31, 286–290 (2005). https://doi.org/10.1007/s11173-005-0090-6

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  • DOI: https://doi.org/10.1007/s11173-005-0090-6

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