Abstract
Sulfur-containing oligomers comprising C—S—C and C—S—S—C moieties were syntesized via the condensation of 1,2-dichloroethane with a mixture of potassium sulfide and disulfide. Cleavage of disulfide bonds in these oligomers with the hydrazine hydrate–KOH system led to the formation of α,ω-potassium dithiolates containing several ethylene sulfide S—C—C—S moieties in the chain. Alkylation of the dithiolates with iodomethane allowed obtaining compounds containing monosulfide moieties. Such compounds can be used as extractants, sorbents, and catalysts and can find applications in various fields, including microbiology, biotechnology, medicine, and agriculture.
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Acknowledgements
The authors are grateful to the Baikal Analytical Center for Collective Use of the Siberian Branch of the Russian Academy of Sciences for the access to research equipment used in this work.
Funding
This work was financially supported by the Russian Science Foundation and the Government of the Irkutsk Region of the Russian Federation (Project No. 23-26-10007).
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 73, No. 3, pp. 738–742, March, 2024.
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Grabelnykh, V.A., Vilms, A.I., Bezborodov, V.A. et al. Yperite-free method for the synthesis of polydentate sulfur-containing ligands. Russ Chem Bull 73, 738–742 (2024). https://doi.org/10.1007/s11172-024-4185-y
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DOI: https://doi.org/10.1007/s11172-024-4185-y