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Optically transparent (co)polyimides based on alicyclic diamines with improved dielectric properties

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Abstract

It was shown that the optical and dielectric properties of polyimides (PIs) are affected by both the presence of an alicyclic fragment and the non-coplanarity of the structural elements of the polymer chain. The combination of these factors contributed to an increase of the transparency of the PIs in the optical range and a decrease of the dielectric constant. It was determined that the introduction of 20 mol.% adamantane-containing diamine into the PI structure contributed to its more complete amorphization and increased its transparency.

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Authors and Affiliations

  1. Federal State Budgetary Educational Institution of Higher Education, Volgograd State Technical University, 28 prosp. im. Lenina, 400005, Volgograd, Russian Federation

    I. A. Novakov, B. S. Orlinson, D. V. Zavialov, S. V. Mednikov, L. M. Gurevich, A. I. Bogdanov, E. N. Saveliev, E. A. Alykova, M. A. Nakhod, A. M. Pichugin, M. N. Kovaleva & D. A. Nilidin

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  1. I. A. Novakov
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  2. B. S. Orlinson
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  3. D. V. Zavialov
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  4. S. V. Mednikov
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  5. L. M. Gurevich
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  6. A. I. Bogdanov
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  7. E. N. Saveliev
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  8. E. A. Alykova
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  9. M. A. Nakhod
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  10. A. M. Pichugin
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  11. M. N. Kovaleva
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  12. D. A. Nilidin
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Corresponding author

Correspondence to E. A. Alykova.

Additional information

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation in the framework of the Russian state assignment (Project FZUS-2021-0013).

The studies were carried out using the equipment of the Physical and Chemical Research Methods Center for Collective Use of the Volgograd State Technical University.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 6, pp. 1366–1376, June, 2023.

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Novakov, I.A., Orlinson, B.S., Zavialov, D.V. et al. Optically transparent (co)polyimides based on alicyclic diamines with improved dielectric properties. Russ Chem Bull 72, 1366–1376 (2023). https://doi.org/10.1007/s11172-023-3911-1

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  • DOI: https://doi.org/10.1007/s11172-023-3911-1

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