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Synthesis and properties of new transparent (co)polyimides based on adamantane-containing diamines and aromatic tetracarboxylic dianhydrides

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Abstract

New (co)polyimides possessing good thermal and physicomechanical characteristics, high hydrolytic stability, and transparency at the best world level were synthesized. It was shown that, depending on the natures of diamine and dianhydride used in the synthesis, the optical properties of polymers also change. These properties of (co)polyimide films correlate with the ΔE value, which is defined as the difference between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) energies of the polyimide repeating unit. It was shown that the use of 1,2-dichlorobenzene makes it possible to obtain high-molecular-weight (co)polyimides with a set of enhanced performance characteristics.

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Authors and Affiliations

  1. Volgograd State Technical University, 28 prosp. im. Lenina, 400005, Volgograd, Russian Federation

    I. A. Novakov, B. S. Orlinson, D. V. Zav’yalov, S. V. Mednikov, E. N. Savel’ev, E. A. Potaenkova, M. A. Nakhod, A. M. Pichugin, A. V. Kireeva & M. N. Kovaleva

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  1. I. A. Novakov
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  2. B. S. Orlinson
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  3. D. V. Zav’yalov
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  4. S. V. Mednikov
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  5. E. N. Savel’ev
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  6. E. A. Potaenkova
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  7. M. A. Nakhod
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  8. A. M. Pichugin
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  9. A. V. Kireeva
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  10. M. N. Kovaleva
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Corresponding author

Correspondence to E. A. Potaenkova.

Additional information

Dedicated to Academician of the Russian Academy of Sciences V. N. Charushin on the occasion of his 70th birthday.

Published in Russian in Izyestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1141–1148, June, 2021.

The study was carried out using using equipment of the Center for Collective Use “Physicochemical Investigation Methods” of the Volgograd State Technical University.

The study was financially supported by the Russian Foundation for Basic Research (Project No. 19-33-90119-19).

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Novakov, I.A., Orlinson, B.S., Zav’yalov, D.V. et al. Synthesis and properties of new transparent (co)polyimides based on adamantane-containing diamines and aromatic tetracarboxylic dianhydrides. Russ Chem Bull 70, 1141–1148 (2021). https://doi.org/10.1007/s11172-021-3196-1

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  • DOI: https://doi.org/10.1007/s11172-021-3196-1

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