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Synthesis of energetic 6-substituted 2,4,8,10,12-pentanitrohexaazaisowurtzitanes

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Abstract

A series of novel energetic 2,4,8,10,12-pentanitrohexaazaisowurtzitanes bearing explosophores in the five-membered ring were synthesized using the reactions between 6-methoxymethyl-2,4,8,10,12-pentanitrohexaazaisowurtzitane and trinitromethane or between 6-chloromethyl-2,4,8,10,12-pentanitrohexaazaisowurtzitane and azides or nitrourethane salts followed by certain substitution reactions. The energy characteristics of the compounds synthesized were calculated.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    T. V. Ternikova, G. V. Pokhvisneva, N. I. Shlykova, S. D. Budina & G. A. Smirnov

  2. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    S. D. Budina

Authors
  1. T. V. Ternikova
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  2. G. V. Pokhvisneva
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  3. N. I. Shlykova
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  4. S. D. Budina
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  5. G. A. Smirnov
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Corresponding author

Correspondence to G. V. Pokhvisneva.

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No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 5, pp. 1240–1246, May, 2023.

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Ternikova, T.V., Pokhvisneva, G.V., Shlykova, N.I. et al. Synthesis of energetic 6-substituted 2,4,8,10,12-pentanitrohexaazaisowurtzitanes. Russ Chem Bull 72, 1240–1246 (2023). https://doi.org/10.1007/s11172-023-3895-x

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  • DOI: https://doi.org/10.1007/s11172-023-3895-x

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