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New o-benzoquinones substituted with tert-octyl groups

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Abstract

A series of o-benzoquinones containing 2,4,4-trimethyl-2-pentyl (tert-octyl) substituents were synthesized. The stability of the reduced forms of the synthesized o-quinones and the electron density distribution in the corresponding radical anion species were studied by cyclic voltammetry and EPR spectroscopy.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    T. N. Kocherova, N. O. Druzhkov, M. V. Arsenyev, E. V. Baranov, V. A. Kuropatov & V. K. Cherkasov

Authors
  1. T. N. Kocherova
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  2. N. O. Druzhkov
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  3. M. V. Arsenyev
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  4. E. V. Baranov
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  5. V. A. Kuropatov
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  6. V. K. Cherkasov
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Corresponding author

Correspondence to T. N. Kocherova.

Additional information

This study was financially supported by the Council on Grants at the President of the Russian Federation (Programs for State Support of Young Russian Scientists and State Support of Leading Scientific Schools of the Russian Federation, Grant No. NSh-403.2022.1.3) using the equipment of the Analytical Center of the G. A. Razuvaev Institute of Organo-metallic Chemistry of the Russian Academy of Sciences (Grant “Ensuring the Development of the Material and Technical Infrastructure of the Centers for Collective Use of Scientific Equipment,” unique identifier RF—2296.61321X0017, agreement number 075-15-2021-670).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Deceased.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 5, pp. 1192–1202, May, 2023.

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Kocherova, T.N., Druzhkov, N.O., Arsenyev, M.V. et al. New o-benzoquinones substituted with tert-octyl groups. Russ Chem Bull 72, 1192–1202 (2023). https://doi.org/10.1007/s11172-023-3889-8

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  • DOI: https://doi.org/10.1007/s11172-023-3889-8

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