Abstract
Temperature-dependent luminescence of polymer compositions doped with boron difluoride β-diketonates was revealed. At room temperature, the samples are characterized by yellow-green luminescence, which turns blue on heating. The mechanism of the temperature-dependent luminescence consists in the dissociation of J-aggregates of dyes on heating. The dissociation of J-aggregates is reversible. The luminescent polymer compositions studied are promising for the development of temperature sensors.
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This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (No. FWFN (0205)-2022-0003).
No human or animal subjects were used in this research.
The authors declare no competing interests.
Anatoly Grigoryevich Mirochnik, born in 1953, Doctor of Science (Chem.), Head of Laboratory of the Federal State Budgetary Institution of Science the Institute of Chemistry of the Far-Eastern Branch of the Russian Academy of Sciences. He is a specialist in the field of physical chemistry of coordination compounds of lanthanoids and p-elements, their application in the design of new polyfunctional optical materials for agriculture, optoelectronics, and ecology. A. G. Mirochnik is the author of more than 200 articles in high-ranking Russian and international journals, one monograph, and 12 patents. The Hirsch index is 19 (Web of Science). Three Candidate of Science and two Doctor of Science theses were defended under the supervision of A. G. Mirochnik. He is a member of the board of the Mendeleev Russian Chemical Society, a member of the editorial board of the journal Vestnik of the FEB RAS, a member of the Organizing Committee of the International Conference on Spectroscopy of Coordination Compounds, an expert at the RAS and RFBR, and a member of dissertation councils at the Institute of Chemistry of the FEB RAS and FEFU.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 1, pp. 223–232, January, 2023.
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Mirochnik, A.G., Fedorenko, E.V. Temperature-dependent luminescence of boron difluoride β-diketonates. Formation and dissociation of J-aggregates. Russ Chem Bull 72, 223–232 (2023). https://doi.org/10.1007/s11172-023-3727-z
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DOI: https://doi.org/10.1007/s11172-023-3727-z