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Two-dimensional ZnII coordination polymer based on 5-iodoisophthalate: synthesis, crystal and electronic structure

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Abstract

The reaction of zinc(II) nitrate with 5-iodoisophthalic acid (5-I-IPAH) in N,N-dimethylformamide afforded the layered coordination polymer {Zn(5-I-IPA)}n(1). The structure of 1 was determined by single-crystal X-ray diffraction. The phase purity of 1 was confirmed by powder X-ray diffraction. The molecular electrostatic potentials of iodine atoms, which characterize their ability to form a halogen bond, were determined by quantum chemical calculations.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    A. S. Zaguzin, M. I. Rakhmanova, V. P. Fedin & S. A. Adonin

  2. South Ural State University, 76 prosp. Lenina, 454080, Chelyabinsk, Russian Federation

    A. S. Zaguzin, D. A. Zherebtsov & S. A. Adonin

  3. St. Petersburg State University, Research Park, 7-9 Universitetskaya nab., 199034, St. Petersburg, Russian Federation

    D. V. Spiridonova

  4. Institute of Chemistry, St. Petersburg State University, 7-9 Universitetskaya nab., 199034, St. Petersburg, Russian Federation

    A. S. Novikov

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  1. A. S. Zaguzin
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  2. D. V. Spiridonova
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  4. M. I. Rakhmanova
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Correspondence to S. A. Adonin.

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This study was financially supported by the Russian Science Foundation (Project No. 21-73-20019) and in part by the Ministry of Science and Higher Education of the Russian Federation (state assignment No. 121031700313-8, study of luminescence properties).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Vladimir Petrovich Fedin, born in 1954, Doctor of Chemical Sciences, Professor, Corresponding Member of the Russian Academy of Sciences, Chief Researcher at the Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences (Novosibirsk), Head of the Chair of Inorganic Chemistry at the Novosibirsk State University, Candidate for Academician of the Russian Academy of Sciences in the elections of 2022. V. P. Fedin is a prominent specialist in the field of coordination and supramolecular chemistry, the author and co-author of more than 600 scientific publications. His research demonstrated that the targeted construction of highly ordered supramolecular systems with specified structures and functional properties can be performed using nanosized building blocks (chalcogenide clusters, polyoxometalates, macrocyclic cavitands) capable of highly specific controlled intermolecular interactions; he developed a methodology for the synthesis of isoreticular nanoporous metal-organic frameworks, which are new adsorbents for the storage and fine purification of gases, catalysts for a wide range of reactions, sensors, and proton-conducting materials; designed unique homochiral porous coordination polymers, which are used for the separation of practically important compounds. He prepared and delivers a course of lectures on inorganic chemistry at the Novosibirsk State University. V. P. Fedin is the Editor-in-Chief of the Journal of Structural Chemistry, an editorial board member of the Russian Chemical Bulletin, Chemistry for Sustainable Development, Russian Journal of Inorganic Chemistry, Journal of Cluster Science, and Crystals; the Chairman of the Dissertation Council for Doctoral and Ph. D. Theses at the NIIC SB RAS.

Sergei Aleksandrovich Adonin, born in 1987, Doctor of Chemical Sciences, Assistant Professor, Leading Researcher at the Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences (Novosibirsk). He was elected as Professor of the Russian Academy of Sciences in 2022. The author and co-author of more than 140 scientific publications. His research interests focus on coordination and supramolecular chemistry. In 2015–2020, S. A. Adonin taught the course of general and inorganic chemistry for foreign students at the V. Zelman Institute for Medicine and Psychology of the Novosibirsk State University. S. A. Adonin is an expert of the Russian Academy of Sciences and the Russian Science Foundation, an editorial board member of the INEOS OPEN; since 2015, a member of the Coordinating Council on Youth in the scientific and educational spheres of the Council under the President of the Russian Federation for Science and Education. S. A. Adonin is an award finalist of the Reaxys PhD Prize (2013), an award winner of the European Academy for young scientists of Russia (2013), a holder of a nominal scholarship of the Government of the Novosibirsk region (2010), a scholarship from Haldor Topsoe (2010); an award winner of the Fernando Pulidori Prize (2017), the prize named after Academician Volpin (2017), the Reaxys Award Russia (2019), a nominal first class prize of the Government of the Novosibirsk region in nomination “Best Supervisor” (2020), a Struchkov Prize winner (2018), awarded with an honorary diploma of the Siberian Branch of the Russian Academy of Sciences (2017).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 1, pp. 177–183, January, 2023.

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Zaguzin, A.S., Spiridonova, D.V., Novikov, A.S. et al. Two-dimensional ZnII coordination polymer based on 5-iodoisophthalate: synthesis, crystal and electronic structure. Russ Chem Bull 72, 177–183 (2023). https://doi.org/10.1007/s11172-023-3722-4

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