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Hybrid macrocyclic polyoxoanions based on {Mo3S4}4+ and γ-[SiW10O36]8− as inorganic ligands

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Abstract

The polyoxoanion [{Mo3S4(H2O)4(tu)}2{Mo3S4(H2O)3(tu)2}2(γ-SiW10O36)4]16− was obtained by the reaction of lacunary silicotungstate [γ-SiW10O36]8− with the trinuclear cluster cation Mo3S4(tu)8(H2O)]4+ (tu is thiourea, (NH2)2CS)). Its reaction with copper(I) iodide in the presence of chloride anions affords tetracubane polyoxometalate [{Mo3S4Cu(H2O)5}4Cl(γ-SiW10O36)4]13−, and the reaction with silver acetate gives the previously described [{Mo3S4(H2O)5}4(γ-SiW10O36)4]16−. The compounds were isolated as potassium sodium salts and structurally characterized.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Acad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    V. S. Korenev, T. S. Sukhikh & M. N. Sokolov

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  1. V. S. Korenev
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Correspondence to V. S. Korenev.

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The work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 121031700313-8).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Maksim Nailevich Sokolov, born in 1967, Chief Researcher at the A. V. Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences, Professor, Professor of the Russian Academy of Sciences, candidate for Corresponding Member of the Russian Academy of Sciences in the elections in 2022, expert in the field of inorganic chemistry. He is an author and co-author of 510 scientific articles. He developed the chemistry of polynuclear and cluster compounds of transition and post-transition metals and studied in details polyoxometalates, halides, and chalcogenides, complexes of heavy transition metals, including noble metals, polyhalide complexes. He discovered a new class of luminescent materials with high quantum yields and proposed new MRT and X-ray contrast agents and materials for photovoltaic cells. He is a member of the editorial board of the “Journal of Structural Chemistry”, a member of the Scientific Council of the A. V. Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences and the Dissertation Council for defending PhD and Dr Sci at the same Institute.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 1, pp. 158–166, January, 2023.

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Korenev, V.S., Sukhikh, T.S. & Sokolov, M.N. Hybrid macrocyclic polyoxoanions based on {Mo3S4}4+ and γ-[SiW10O36]8− as inorganic ligands. Russ Chem Bull 72, 158–166 (2023). https://doi.org/10.1007/s11172-023-3720-6

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