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Metal-polymer nanocomposites based on metal-containing monomers

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Russian Chemical Bulletin Aims and scope

Abstract

A detailed analysis of the latest achievements in the field of preparing promising metal-polymer nanocomposites by the conjugated thermolysis of metal-containing monomers as precursors was carried out. The general scheme of conjugated thermolysis includes three successive stages: dehydration (desolvation), polymerization, and thermolysis of the formed metal polymers. The kinetic schemes and reactions of thermal transformation of metal-containing monomers are analyzed. Particular attention is paid to the compositions and structures of the resulting metal-polymer nanocomposites. The use of the prepared nanocomposites as tribological and magnetic materials, sensors, and catalysts is generalized. The problems and prospects for the preparation of new nanomaterials using conjugated thermolysis of metal-containing monomers are considered.

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Funding

This work was financially supported by the Russian Science Foundation (Project No. 22-13-00260).

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Authors and Affiliations

  1. Institute for Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russia

    G. I. Dzhardimalieva

  2. Moscow Aviation Institute, National Research University, 4 Volokolamskoe sh., 125993, Moscow, Russia

    G. I. Dzhardimalieva

  3. Southern Federal University, 7 ul. Zorge, 344090, Rostov-on-Don, Russia

    I. E. Uflyand & V. A. Zhinzhilo

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  1. G. I. Dzhardimalieva
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  2. I. E. Uflyand
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  3. V. A. Zhinzhilo
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Correspondence to V. A. Zhinzhilo.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2052–2075, October, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Dzhardimalieva, G.I., Uflyand, I.E. & Zhinzhilo, V.A. Metal-polymer nanocomposites based on metal-containing monomers. Russ Chem Bull 71, 2052–2075 (2022). https://doi.org/10.1007/s11172-022-3628-6

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