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Kinetic regularities of thermal decomposition of polycarbonate films containing Pt, Au, Ag, and Ni nanoparticles

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Abstract

The kinetic regularities of thermal destruction of polycarbonate films containing Pt, Au, Ag, and Ni nanoparticles were studied. Scanning and transmission electron microscopy, as well as surface plasmon resonance absorption spectra, were used to determine the sizes and shapes of metal nanoparticles in composite films. Nanocomposites were obtained by various methods: by reduction of a precursor in a polycarbonate solution followed by evaporation of the solvent; by deposition on a polymer film surface of nanoparticles formed as a result of diode sputtering of metal in argon plasma or laser ablation in superfluid helium. The rate of thermal decomposition of polycarbonate nanocomposites exceeded the rate of decomposition of the starting polymer. The highest catalytic ability was exhibited by Pt, Au, and Ni nanoparticles in the form of nanowires with diameters of 2–6 nm.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    N. N. Volkova, L. M. Bogdanova, A. V. Karabulin & M. G. Spirin

  2. Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, 6 prosp. Akad. Osip’yana, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. T. Volkov

  3. Joint Institute for High Temperatures, Russian Academy of Sciences, 13/2 ul. Izhorskaya, 125412, Moscow, Russian Federation

    A. V. Karabulin

  4. Chernogolovka Branch of the N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 1/10 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. I. Matyushenko

Authors
  1. N. N. Volkova
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  2. L. M. Bogdanova
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  3. V. T. Volkov
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  4. A. V. Karabulin
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  5. V. I. Matyushenko
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  6. M. G. Spirin
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Corresponding author

Correspondence to N. N. Volkova.

Additional information

Published in Russian in Izvestiya AkademiiNauk. Seriya Khimicheskaya, No. 9, pp. 1690–1698, September, 2021.

The work was carried out as part of the Russian state assignment (state registration No. AAAA-A19-119101690058-9, No. AAAA-A19-119100800130-0, No. AAAA-A18-118112290069-6, No. AAAA-A19-119070790003-7, and No. AAAA-A19-119032690060-9).

The authors are grateful to the Center for Collective Use of the Scientific Center of the Russian Academy of Sciences in Chernogolovka for studies using the JEM-2100 electron microscope.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Volkova, N.N., Bogdanova, L.M., Volkov, V.T. et al. Kinetic regularities of thermal decomposition of polycarbonate films containing Pt, Au, Ag, and Ni nanoparticles. Russ Chem Bull 70, 1690–1698 (2021). https://doi.org/10.1007/s11172-021-3271-7

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  • DOI: https://doi.org/10.1007/s11172-021-3271-7

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