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Hydrogen spillover on cerium-based catalysts

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Russian Chemical Bulletin Aims and scope

Abstract

Data on hydrogen spillover (HS) in catalytic processes are systematized. Different opinions on the mechanism and participation of HS in various reactions are presented. Hydrogen spillover on CeO2-based systems and physicochemical methods of investigation of the phenomenon are considered. Tentative mechanisms of HS are described and the role of HS in catalytic hydrogenation reactions is studied.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    K. V. Vikanova, E. A. Redina & L. M. Kustov

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 1, 3 Leninskie Gory, 119991, Moscow, Russian Federation

    L. M. Kustov

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  1. K. V. Vikanova
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  2. E. A. Redina
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  3. L. M. Kustov
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Correspondence to K. V. Vikanova.

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Dedicated to Academician of the Russian Academy of Sciences V. A. Tartakovsky on the occasion of his 90th birthday.

This work was financially supported by the Russian Science Foundation (Project No. 20-63-46013).

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1579–1592, August, 2022.

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Vikanova, K.V., Redina, E.A. & Kustov, L.M. Hydrogen spillover on cerium-based catalysts. Russ Chem Bull 71, 1579–1592 (2022). https://doi.org/10.1007/s11172-022-3567-2

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