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Heterogeneous catalytic condensation of propanal

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Abstract

The aldol homocondensation of propanal was studied in the presence of a heterogeneous titanium oxide catalyst modified with amino acid (AA) l-norleucine. The effects of the temperature and l-norleucine content on the conversion of propanal and selectivity of the process were studied. The reaction products were identified, and possible mechanisms are considered. A new catalyst (5% AA on titanium dioxide) was developed for the synthesis of 2-methyl-2-pentenal with the selectivity >90%.

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Authors and Affiliations

  1. MIREA - Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technologies, 78 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    E. M. Martsinkevich, A. A. Afaunov, V. R. Flid & L. G. Bruk

Authors
  1. E. M. Martsinkevich
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  2. A. A. Afaunov
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  3. V. R. Flid
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  4. L. G. Bruk
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Corresponding author

Correspondence to E. M. Martsinkevich.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2031–2033, October, 2021.

This work was carried out using equipment of the Center for Collective Use of the Russian Technological University (MIREA) financially supported by the Ministry of Education and Science of the Russian Federation.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Martsinkevich, E.M., Afaunov, A.A., Flid, V.R. et al. Heterogeneous catalytic condensation of propanal. Russ Chem Bull 70, 2031–2033 (2021). https://doi.org/10.1007/s11172-021-3313-1

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  • DOI: https://doi.org/10.1007/s11172-021-3313-1

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