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Effect of ATP and amino acids on the properties of cationic amphiphiles in solution and on the surface

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Abstract

The interaction between a number of cationic surfactants bearing the head group with different structures (triallyl, morpholinium, including hydroxyethyl-substituted) with oppositely charged biomolecules (amino acids and sodium adenosine triphosphate (ATP)) was studied. The amino acid additives (glycine, lysine, histidine, arginine) do not affect the aggregation behavior of the tested cationic surfactants. However, in some combinations, they can significantly increase their solubilization capacity. The ATP additive already in a minimum amount decreases the critical micelle concentration of the surfactant by an order of magnitude, and the solubilization capacity depends on the structure of the surfactant head group.

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Correspondence to E. A. Vasilieva.

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Dedicated to Academician of the Russian Academy of Sciences V. I. Ovcharenko on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1519–1526, July, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Vasilieva, E.A., Kuznetsova, D.A., Gaynanova, G.A. et al. Effect of ATP and amino acids on the properties of cationic amphiphiles in solution and on the surface. Russ Chem Bull 71, 1519–1526 (2022). https://doi.org/10.1007/s11172-022-3559-2

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  • DOI: https://doi.org/10.1007/s11172-022-3559-2

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