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Oxidation of benzyl alcohol in the copper-doped ZIF-8 metal-organic framework with encapsulated nitroxyl radical

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Abstract

A novel heterogeneous catalytic system based on the TEMPO nitroxyl radical encapsulated into the cavities of copper-doped ZIF-8 metal-organic framework was synthesized and characterized using ESR spectroscopy and powder X-ray diffraction. This system provided a highly selective (>99%) oxidation of benzyl alcohol to benzaldehyde.

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Authors and Affiliations

  1. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russia

    A. A. Efremov, A. S. Poryvaev, D. M. Polyukhov & M. V. Fedin

  2. Novosibirsk National Research State University, 1 ul. Pirogova, 630090, Novosibirsk, Russia

    A. A. Efremov, S. A. Gromilov & M. V. Fedin

  3. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russia

    S. A. Gromilov

Authors
  1. A. A. Efremov
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  2. A. S. Poryvaev
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  3. D. M. Polyukhov
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  4. S. A. Gromilov
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  5. M. V. Fedin
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Corresponding authors

Correspondence to S. A. Gromilov or M. V. Fedin.

Additional information

Dedicated to Academician of the Russian Academy of Sciences V. I. Ovcharenko on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1422–1428, July, 2022.

The authors are grateful to S. A. Prikhod’ko and N. Yu. Adonin, colleagues from the Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, who performed preliminary catalytic experiments.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Efremov, A.A., Poryvaev, A.S., Polyukhov, D.M. et al. Oxidation of benzyl alcohol in the copper-doped ZIF-8 metal-organic framework with encapsulated nitroxyl radical. Russ Chem Bull 71, 1422–1428 (2022). https://doi.org/10.1007/s11172-022-3548-5

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  • DOI: https://doi.org/10.1007/s11172-022-3548-5

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