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Radical recombination in ultrahigh magnetic fields

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Abstract

The effect of ultrahigh magnetic field (UMF; tens of Tesla) on the recombination kinetics of short-lived radicals in the liquid phase is studied. The influence of the well-known radical-pair mechanism of the magnetic field effect (MFE) in radical chemical reactions and the mechanism of equilibrium thermodynamic alignment of spins of the unpaired electrons of the radicals in UMF on the rate of spin-selective radical recombination is considered. For both mechanisms, the recombination rate constants were calculated using the theory of diffusion-controlled reactions in solution. The contributions of the two mechanisms to the experimentally observed MFE in the recombination of NO• radical and the superoxide radical anion affording peroxynitrite in 18 T magnetic field are estimated.

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Funding

This work was financially supported by the Russian Foundation for Basic Research (Project No. 20-03-00234).

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Authors and Affiliations

  1. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russia

    M. V. Petrova & N. N. Lukzen

  2. V. V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 ul. Institutskaya, 630090, Novosibirsk, Russia

    D. V. Stass

Authors
  1. M. V. Petrova
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  2. D. V. Stass
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  3. N. N. Lukzen
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Corresponding authors

Correspondence to D. V. Stass or N. N. Lukzen.

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Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2347–2353, December, 2021.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Petrova, M.V., Stass, D.V. & Lukzen, N.N. Radical recombination in ultrahigh magnetic fields. Russ Chem Bull 70, 2347–2353 (2021). https://doi.org/10.1007/s11172-021-3351-8

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