Skip to main content
SpringerLink
Log in

Effect of MQ-copolymer and polymethylsilsesquioxane on thermal and mechanical properties of highly filled polyisoprene

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Highly filled vulcanizates based on polyisoprene, organosilicon fillers (polymethylsilsesquioxane and MQ-copolymers), and p-quinone dioxime derivative as a rubber cross-linking agent were prepared. The properties of model rubbers are compared with those formed on the basis of the same elastomer with standard reinforcing fillers, namely, carbon black and aerosil. The effect of fillers on the thermal and mechanical properties of cross-linked objects is estimated. The presence of organosilicon compounds as fillers increases the thermal stability of the composites, and in the case of polymethylsilsesquioxane, both the strength and the tensile modulus of vulcanizates are increased in comparison with rubbers based on standard fillers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. E. Mark, B. Erman, F. R. Eirich, Science and Technology of Rubber, Acad. Press, New York, 2005, 751 pp.

    Google Scholar 

  2. O. A. Serenko, A. M. Muzafarov, Polym. Sci. Ser. C, 2016, 58, 93; DOI: https://doi.org/10.7868/S2308114716010118.

    Article  CAS  Google Scholar 

  3. W. Chonkaew, W. Mingvanish, U. Kungliean, N. Rochanawipart, W. Brostow, J. Nanosci. Nanotechnol., 2011, 11, 2018; DOI: https://doi.org/10.1166/jnn.2011.3563.

    Article  CAS  Google Scholar 

  4. Y. Li, B. Han, L. Liu, F. Zhang, L. Zhang, S. Wen, Y. Lu, H. Yang, J. Shen, Compos. Sci. Technol., 2013, 88, 69; DOI: https://doi.org/10.1016/j.compscitech.2013.08.029.

    Article  CAS  Google Scholar 

  5. I. A. Novakov, N. K. Dang, M. A. Vaniev, N. V. Sidorenko, Russ. Chem. Bull., 2013, 62, 276; DOI: https://doi.org/10.1007/s11172-013-0041-1.

    Article  CAS  Google Scholar 

  6. K. Katueangngan, T. Tulyapitak, A. Saetung, S. Soontaranon, N. Nithi-uthai, Procedia Chemistry., 2016, 19, 447; DOI: https://doi.org/10.1016/j.proche.2016.03.037.

    Article  CAS  Google Scholar 

  7. A. I. Medalia, Encyclopedia of Materials: Science and Technology, 2001, p. 2475.

  8. C. Zhang, Z. Tang, B. Guo, L. Zhang, Compos. Sci. Technol., 2019, 169, 217; DOI: https://doi.org/10.1016/j.compscitech.2018.11.016.

    Article  CAS  Google Scholar 

  9. M. Castellano, L. Conzatti, A. Turturro, G. Costa, G. Busca, J. Phys. Chem. B, 2007, 111, 4495; DOI: https://doi.org/10.1021/jp0702144.

    Article  CAS  Google Scholar 

  10. X. Wang, L. Wu, H. Yu, T. Xiao, H. Li, J. Yang, Polymer Testing, 2020, 91, 106840; DOI: https://doi.org/10.1016/j.polymertesting.2020.106840.

    Article  CAS  Google Scholar 

  11. L. Chen, Z. Jia, Y. Tang, L. Wu, Y. Luo, D. Jia, Compos. Sci. Technol., 2017, 144, 11; DOI: https://doi.org/10.1016/j.compscitech.2016.11.005.

    Article  CAS  Google Scholar 

  12. C. Zhang, Z. Tang, B. Guo, L. Zhang, Compos. Sci. Technol., 2018, 156, 70; DOI: https://doi.org/10.1016/j.compscitech.2017.12.020.

    Article  CAS  Google Scholar 

  13. O. A. Serenko, T. A. Pryakhina, V. G. Vasil’ev, M. I. Buzin, I. O. Volkov, V. M. Kotov, A. M. Muzafarov, Russ. Chem. Bull., 2021, 70, 960; DOI: https://doi.org/10.1007/s11172-021-3173-8.

    Article  CAS  Google Scholar 

  14. A. I. Amirova, O. V. Golub, D. A. Migulin, A. M. Muzafarov, Int. J. Polym. Anal. Charact., 2016, 21, 214; DOI: https://doi.org/10.1080/1023666X.2016.1136867.

    Article  CAS  Google Scholar 

  15. I. B. Meshkov, A. A. Kalinina, V. V. Kazakova, A. I. Demchenko, INEOS OPEN, 2020, 3, 118; DOI: https://doi.org/10.32931/io2022r.

    Article  CAS  Google Scholar 

  16. N. V. Voronina, I. B. Meshkov, V. D. Myakushev, T. V. Laptinskaya, V. S. Papkov, M. I. Buzin, M. N. Il’ina, A. N. Ozerin, A. M. Muzafarov, J. Polym. Sci. Part A, 2010, 48, 4310; DOI: https://doi.org/10.1002/pola.24219.

    Article  CAS  Google Scholar 

  17. O. A. Serenko, V. G. Shevchenko, A. S. Zhiltsov, T. V. Zaderenko, O. T. Gritsenko, O. B. Gorbatsevich, V. V. Kazakova, A. M. Muzafarov, V. E. Chuprakov, M. V. Mironova, V. G. Kulichikhin, Nanotechnol. Russia, 2013, 8, 81; DOI: https://doi.org/10.1134/S1995078013010138.

    Article  Google Scholar 

  18. M. N. Temnikov, S. N. Zimovets, V. G. Vasil’ev, M. I. Buzin, INEOS OPEN, 2020, 3, 112; DOI: https://doi.org/10.32931/io2012a.

    Article  CAS  Google Scholar 

  19. D. Migulin, E. Tatarinova, I. Meshkov, G. Cherkaev, N. Vasilenko, M. Buzin, A. Muzafarov, Polym. Int., 2016, 65, 72; DOI: https://doi.org/10.1002/pi.5029.

    Article  CAS  Google Scholar 

  20. E. Tatarinova, N. Vasilenko, A. Muzafarov, Molecules, 2017, 22, 1768; DOI: https://doi.org/10.3390/molecules22101768.

    Article  Google Scholar 

  21. O. A. Serenko, A. M. Muzafarov, M. V. Mironova, V. G. Kulichikhin, N. A. Novozhilova, P. V. Strashnov, E. V. Getmanova, V. G. Shevchenko, A. A. Askadskii, Mater. Chem. Phys., 2015, 156, 16; DOI: https://doi.org/10.1016/j.matchemphys.2015.02.013.

    Article  CAS  Google Scholar 

  22. S. S. Sarkawi, W. K. Dierkes, J. W. M. Noordermeer, Eur. Polym. J., 2014, 54, 118; DOI: https://doi.org/10.1016/j.eurpolymj.2014.02.015.

    Article  CAS  Google Scholar 

  23. S. Samarzija-Jovanovic, V. Jovanovic, G. Markovic, M. Marinovic-Cincovic, J. Therm. Anal. Calorim., 2009, 98, 275; DOI https://doi.org/10.1007/s10973-009-0131-3.

    Article  CAS  Google Scholar 

  24. Y. Merckel, J. Diani, M. Brieu, J. Caillard, J. Appl. Polym. Sci., 2013, 129, 2086; DOI: https://doi.org/10.1002/app.38925.

    Article  CAS  Google Scholar 

  25. M. V. Mironova, G. A. Shandryuk, A. A. Shabeko, I. B. Meshkov, V. G. Kulichikhin, A. M. Muzafarov, Polym. Sci. Ser. B., 2021, 63, 199; DOI: https://doi.org/10.31857/S2308113921030116.

    Article  CAS  Google Scholar 

  26. I. B. Meshkov, N. G. Mazhorova, P. V. Zhemchugov, A. A. Kalinina, S. G. Vasil’ev, A. V. Bystrova, S. E. Lyubimov, A. S. Tereshchenko, A. M. Muzafarov, INEOS OPEN, 2019, 2, 140; DOI: https://doi.org/10.32931/io1920a.

    Article  CAS  Google Scholar 

  27. Pat. SU 1594173 A1, 1990.

  28. L. M. Gan, C. H. Chew, Rubber Chem. Technol, 1983, 56, 883; DOI: https://doi.org/10.5254/1.3538170.

    Article  CAS  Google Scholar 

  29. I. O. Klyuchnikov, O. R. Klyuchnikov, O. V. Stoyanov, Polym. Sci. Ser. D., 2016, 9, N№ 2, 157; DOI: https://doi.org/10.1134/S199542121602009X.

    Article  CAS  Google Scholar 

  30. M. V. Mironova, I. B. Meshkov, A. A. Shabeko, V. V. Shutov, V. G. Kulichikhin, E. A. Tatarinova, INEOS OPEN, 2020, 3, 29; DOI: https://doi.org/10.32931/io2004a.

    Article  CAS  Google Scholar 

  31. H. H. Winter, Polym. Eng. Sci., 1987, 27, 1698; DOI: https://doi.org/10.1002/pen.760272209.

    Article  CAS  Google Scholar 

  32. B. S. Chiou, S. R. Raghavan, S. A. Khan, Macromolecules, 2001, 34, 4526; DOI: https://doi.org/10.1021/ma010281a.

    Article  CAS  Google Scholar 

  33. K. L. Mok, A. Eng, Malaysian J. Chem., 2018, 20, 118.

    Google Scholar 

  34. O. P. Kuznetsova, L. A. Zhorina, E. V. Prut, Vysokomol. soed, Ser. A. 2004, 46, 275 [Polym. Sci., Ser. A., 2004, 46] (in Russian).

    CAS  Google Scholar 

  35. G. Kraus, J. Appl. Polym. Sci., 1963, 7, 861; DOI: https://doi.org/10.1002/app.1963.070070306.

    Article  CAS  Google Scholar 

  36. H. Schott, J. Pharm. Sci., 1992, 81, 467; DOI: https://doi.org/10.1002/jps.2600810516.

    Article  CAS  Google Scholar 

  37. H. Schott, J. Macromol. Sci. Physics, 1992, 31, 1; DOI: https://doi.org/10.1080/00222349208215453.

    Article  CAS  Google Scholar 

Download references

Funding

The work was financially supported by the Russian Foundation for Basic Research (Project No. 18-33-20247).

Fillers were synthesized under financial support by the Russian Foundation for Basic Research (Project No. 18-29-25053).

Investigation on the kinetics of swelling were performed in the frameworks of State Program of the A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences.

Author information

Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences, 29 Leninskii prosp., 119991, Moscow, Russian Federation

    M. V. Mironova, G. A. Shandryuk, A. A. Shabeko, I. S. Makarov & V. G. Kulichikhin

  2. N. S. Enikolopov Institute of Synthetic Polymer Materials of the Russian Academy of Sciences, 70 Profsoyuznaya ul., 117999, Moscow, Russian Federation

    I. B. Meshkov & A. M. Muzafarov

Authors
  1. M. V. Mironova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. A. Shandryuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. B. Meshkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Shabeko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. S. Makarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. G. Kulichikhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. M. Muzafarov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to M. V. Mironova or I. B. Meshkov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2200–2207, November, 2021.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mironova, M.V., Shandryuk, G.A., Meshkov, I.B. et al. Effect of MQ-copolymer and polymethylsilsesquioxane on thermal and mechanical properties of highly filled polyisoprene. Russ Chem Bull 70, 2200–2207 (2021). https://doi.org/10.1007/s11172-021-3333-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-021-3333-x

Key words

Search

Navigation