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Coordination polymers of VIV—MII (MII = Mn, Co, Ni, Cd) with ethylmalonate anions

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Abstract

A series of heterometallic 1D coordination polymers {[MII(VIVO)(Etmal)2(H2O)5] • 2 H2O}n (MII = Mn (1), Co (2), Ni (3), Cd (4)) were synthesized. These compounds are composed of oxovanadium(iv)-containing mononuclear anionic units [VIVO(Etmal)2]2− linked by d-metal aqua cations. The X-ray diffraction study showed that the nature of the starting d-metal sulfate in the reactions with VOSO4 • 3 H2O and barium salt of ethylmalonic acid (H2Etmal = C3H6(CO2H)2) has no effect on the structure of the resulting coordination polymer. The magnetic isolation of paramagnetic centers in all the synthesized compounds was confirmed by magnetochemical measurements.

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Funding

The work was financially supported by the Russian Science Foundation (Project No. 19-73-10181).

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. S. Bazhina, M. A. Shmelev, K. A. Babeshkin, N. N. Efimov, M. A. Kiskin & I. L. Eremenko

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  1. E. S. Bazhina
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  2. M. A. Shmelev
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  3. K. A. Babeshkin
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  4. N. N. Efimov
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Correspondence to E. S. Bazhina.

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Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2130–2138, November, 2021.

The C,H,N,S elemental analysis, IR spectroscopy, single-crystal X-ray diffraction studies, powder X-ray diffraction analysis, and magnetochemical measurements were performed using the equipment of the Joint Research Centre of Physical Methods of Research of the N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences (JRC PMR IGIC RAS).

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Bazhina, E.S., Shmelev, M.A., Babeshkin, K.A. et al. Coordination polymers of VIV—MII (MII = Mn, Co, Ni, Cd) with ethylmalonate anions. Russ Chem Bull 70, 2130–2138 (2021). https://doi.org/10.1007/s11172-021-3324-y

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