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Methods for the synthesis of functionalized alkynylcyclopropanes

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Russian Chemical Bulletin Aims and scope

Abstract

Data on methods for the synthesis of various classes of functionalized alkynylcyclopropanes (FACPs) reported in the last two decades are systematized. Synthetic routes to FACPs based on cyclopropanation of unsaturated compounds with various carbenes, carbenoids, and ylides are considered separately. Methods for introducing functional groups into the three-membered ring of alkynylcyclopropanes via metalation and elimination—addition processes as well as other synthetic routes to functionalized cyclopropanes are discussed.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    V. D. Gvozdev, K. N. Shavrin, M. P. Egorov & O. M. Nefedov

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  1. V. D. Gvozdev
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  2. K. N. Shavrin
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  3. M. P. Egorov
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  4. O. M. Nefedov
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Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2051–2083, November, 2021.

This paper does not contain descriptions of studies on animals or humans.

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Gvozdev, V.D., Shavrin, K.N., Egorov, M.P. et al. Methods for the synthesis of functionalized alkynylcyclopropanes. Russ Chem Bull 70, 2051–2083 (2021). https://doi.org/10.1007/s11172-021-3318-9

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