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Microstructure of the chain of alkyl (meth)acrylate copolymers with vinyl butyl ether synthesized by the compensation method

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Abstract

Copolymers of butyl acrylate and methyl methacrylate with vinyl butyl ether in excess at reflux of the latter were synthesized under comparable conditions gradually adding acrylic monomers to the reaction mixture. Azobisisobutyronitrile or a triethylborane—oxygen initiating system was used as the initiator. The molar ratio of the monomer units was determined for the isolated polymers by IR and 1H NMR spectroscopy. The 13C NMR spectra of the copolymers were interpreted in order to determine the degree of alternation of units. The microheterogeneity coefficients and average lengths of sequences of the same chain units determined from the 13C NMR spectra indicate that the copolymer with butyl acrylate has a microstructure close to the alternation of the ether and ester units in the chain, whereas in the copolymer with methyl methacrylate this structure is pronounced to a lower extent.

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Authors and Affiliations

  1. N. I. Lobachevsky Nizhny Novgorod State University, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    L. L. Semenycheva, Yu. O. Matkivskaya, Yu. O. Pegeeva, N. L. Pegeev, N. B. Valetova & T. I. Liogon’kaya

  2. R. E. Alekseev Nizhny Novgorod State Technical University, 24 ul. Minina, 603950, Nizhny Novgorod, Russian Federation

    Yu. A. Kurskii

Authors
  1. L. L. Semenycheva
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  2. Yu. O. Matkivskaya
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  3. Yu. O. Pegeeva
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  4. N. L. Pegeev
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  5. N. B. Valetova
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  6. T. I. Liogon’kaya
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  7. Yu. A. Kurskii
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Corresponding author

Correspondence to L. L. Semenycheva.

Additional information

Based on the materials of the VIII All-Russian Kargin Conference “Polymers-2020” (November 9–13, 2020, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1798–1803, September, 2021.

These studies were carried out using equipment of the Center for Collective Use “Novel Materials and Resource-Saving Technologies” of the Research Institute of Chemistry at the N. I. Lobachevsky Nizhny Novgorod State University.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Semenycheva, L.L., Matkivskaya, Y.O., Pegeeva, Y.O. et al. Microstructure of the chain of alkyl (meth)acrylate copolymers with vinyl butyl ether synthesized by the compensation method. Russ Chem Bull 70, 1798–1803 (2021). https://doi.org/10.1007/s11172-021-3285-1

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  • DOI: https://doi.org/10.1007/s11172-021-3285-1

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