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Silver nanocomposites based on copolymers of N,N-diallyl-N’-acetylhydrazine with N-vinylpyrrolidone

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Abstract

A method was developed for the preparation of polymer silver nanocomposites using copolymer of N, N-diallyl-N’-acetylliydrazine with N-vinylpyrrolidone as reducing agent for silver ions and stabilizer of the obtained nanoparticles in an aqueous-alcoholic and aqueous medium. The obtained polymer nanocomposites consist of isolated silver nanoparticles having predominantly spherical shapes and diameters of 5 to 30 nm. The dependence of particle size on the medium and the concentration of silver ions was observed. The structural features of the nanocomposites were investigated using UV, IR, NMR spectroscopy, SEM microscopy, and powder X-ray diffraction.

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Authors and Affiliations

  1. Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, 3 ul. Koroleva, 614013, Perm, Russian Federation

    M. N. Gorbunova, T. D. Batueva, D. M. Kiselkov & V. N. Strelnikov

Authors
  1. M. N. Gorbunova
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  2. T. D. Batueva
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  3. D. M. Kiselkov
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  4. V. N. Strelnikov
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Corresponding author

Correspondence to M. N. Gorbunova.

Additional information

Based on the materials of the VIII All-Russian Kargin Conference “Polymers-2020” (November 9–13, 2020, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1706–1712, September, 2021.

This work was financially supported by the Russian Foundation for Basic Research and the Perm Krai Government (Project No. 19-43-590019-r_a).

The authors are grateful to the Center for Collective Use of the Perm Federal Research Center of the Ural Branch of the Russian Academy of Sciences “Research of Materials and Substances” for spectral, analytical, and biological studies.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Gorbunova, M.N., Batueva, T.D., Kiselkov, D.M. et al. Silver nanocomposites based on copolymers of N,N-diallyl-N’-acetylhydrazine with N-vinylpyrrolidone. Russ Chem Bull 70, 1706–1712 (2021). https://doi.org/10.1007/s11172-021-3273-5

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  • DOI: https://doi.org/10.1007/s11172-021-3273-5

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