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Synthesis of bimetallic nanoparticles Pd-Au and Pt-Au on carbon nanotubes in an autoclave

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Abstract

The hydrothermal formation of Pd and Pt nanoparticles on carbon nanotubes (CNT) and the subsequent reduction of gold from solutions in these systems were investigated. It was found that upon contact of composites Pd/CNT and Pt/CNT (6.0 wt.%) with hydrogen tetrachloroaurate(iii) solutions in an autoclave, bimetallic particles Pd-Au and Pt-Au, respectively, are formed. The sample composition, structure, and size was investigated by powder X-ray diffraction, scanning and transmission electron microscopy with local energy-dispersive X-ray fluorescence analysis, X-ray photoelectron spectroscopy, and nitrogen gas adsorption.

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Correspondence to R. V. Borisov.

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This work was partially carried out within the framework of the state assignment of the Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences (project No. 0287-2021-0014) using the facilities of the Krasnoyarsk Regional Center for Collective Use of the Federal Research Center “Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences”.

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1474–1482, August, 2021.

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Borisov, R.V., Belousov, O.V., Zhizhaev, A.M. et al. Synthesis of bimetallic nanoparticles Pd-Au and Pt-Au on carbon nanotubes in an autoclave. Russ Chem Bull 70, 1474–1482 (2021). https://doi.org/10.1007/s11172-021-3242-z

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  • DOI: https://doi.org/10.1007/s11172-021-3242-z

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