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Iodine as an efficient and available activator of sodium and potassium halides in carbon dioxide addition to epoxides

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Abstract

Sodium and potassium halides in combination with molecular iodine are efficient catalysts for the solvent-free addition of CO2 (10–56 atm) to epoxides giving organic carbonates.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov & A. A. Zvinchuk

  2. Department of Chemistry, Indian Institute of Technology (Indian School of Mines), Dhanbad, 826004, India

    B. Chowdhury

Authors
  1. S. E. Lyubimov
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  2. A. A. Zvinchuk
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  3. B. Chowdhury
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Corresponding authors

Correspondence to S. E. Lyubimov or B. Chowdhury.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1324–1327, July, 2021.

The authors are grateful to the Center for Investigation of Structure of Molecules at the A. N. Nesmeyanov Institute of Organoelement Compounds (Russian Academy of Sciences) of the Ministry of Science and Higher Education of the Russian Federation for the analyses performed by Raman spectroscopy and valuable advices.

This work was financially supported by the Russian Science Foundation (Project No. 19-43-02031).

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Lyubimov, S.E., Zvinchuk, A.A. & Chowdhury, B. Iodine as an efficient and available activator of sodium and potassium halides in carbon dioxide addition to epoxides. Russ Chem Bull 70, 1324–1327 (2021). https://doi.org/10.1007/s11172-021-3218-z

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  • DOI: https://doi.org/10.1007/s11172-021-3218-z

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