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Polyethylenimine-based catalysts for the addition of carbon dioxide to epoxides: an effect of substituents

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Abstract

A group of available catalysts based on polyethylenimine quaternized with p-xylylene dichloride followed by subsequent exchange of anions was developed. The influence of the nature of halide ions and electronic and steric factors of the substituents in epoxides on the reaction rate of carbon dioxide addition to epoxides was studied. The catalytic capabilities of the adduct of polyethylenimine with iodine were considered.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, A. A. Zvinchuk & R. R. Aysin

  2. Department of Chemistry, Indian Institute of Technology (Indian School of Mines), Dhanbad, 826004, India

    B. Chowdhury

Authors
  1. S. E. Lyubimov
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  2. A. A. Zvinchuk
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  3. R. R. Aysin
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  4. B. Chowdhury
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Corresponding authors

Correspondence to S. E. Lyubimov or B. Chowdhury.

Additional information

The authors are grateful to the Center for Investigation of Structure of Molecules at the A. N. Nesmeyanov Institute of Organoelement Compounds (Russian Academy of Sciences) of the Ministry of Science and Higher Education of the Russian Federation for analyses performed by Raman spectroscopy and valuable advices.

This paper was financially supported by the Russian Science Foundation (Project No. 19-43-02031).

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1533–1536, August, 2021.

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Lyubimov, S.E., Zvinchuk, A.A., Aysin, R.R. et al. Polyethylenimine-based catalysts for the addition of carbon dioxide to epoxides: an effect of substituents. Russ Chem Bull 70, 1533–1536 (2021). https://doi.org/10.1007/s11172-021-3248-6

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  • DOI: https://doi.org/10.1007/s11172-021-3248-6

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