Abstract
New energy-rich derivatives of 2-nitroguanidine were obtained. The synthesis was based on the reaction of 1-chloromethyl-2-nitroguanidine, which was obtained by chlorination of 1-hydroxymethyl-2-nitroguanidine with sodium azide or salts of N-nitramines. The synthesized compounds can be of interest as potential components of both composite solid propellants and explosive compositions.
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T. V. Ternikova, G. V. Pokhvisneva, O. A. Luk’yanov, Russ. Chem. Bull., 2020, 69, 2349.
S. V. Nikitin, G. V. Pokhvisneva, T. V. Ternikova, P. B. Gordeev, I. M. Chistokhvalov, G. A. Smirnov, O. A. Luk’yanov, Russ. Chem. Bull., 2018, 67, 1445.
G. V. Pokhvisneva, P. B. Gordeev, S. V. Nikitin, G. A. Smirnov, T. V. Ternikova, O. A. Luk’yanov, Russ. Chem. Bull., 2018, 67, 1655.
G. A. Smirnov, P. B. Gordeev, S. V. Nikitin, G. V. Pokhvisneva, T. V. Ternikova, I. M. Chistokhvalov, O. A. Luk’yanov, Russ. Chem. Bull., 2018, 67, 1662.
G. A. Smirnov, P. B. Gordeev, S. V. Nikitin, G. V. Pokhvisneva, T. V. Ternikova, I. M. Chistokhvalov, O. A. Luk’yanov, Russ. Chem. Bull., 2018, 67, 2010.
G. A. Smirnov, P. B. Gordeev, O. A. Luk’yanov, Russ. Chem. Bull., 2020, 69, 105.
G. A. Smirnov, P. B. Gordeev, Russ. Chem. Bull., 2020, 69, 2153.
O. A. Luk’yanov, N. I. Shlykova, G. V. Pokhvisneva, T. V. Ternikova, K. A. Monogarov, D. B. Meerov, Yu. V. Nelyubina, P. V. Dorovatovskii, T. S. Kon’kova, Russ. Chem. Bull., 2019, 68, 110.
T. V. Ternikova, G. V. Pokhvisneva, O. A. Luk’yanov, Russ. Chem. Bull., 2011, 68, 1874.
E.-C. Koch, Propellants, Explos., Pyrotech., 2019, 44, 1.
E.-C. Koch, Def. Technol., 2019, 15, 467.
Y. Oyumi, A. L. Rheingold, T. B. Brill, Propellants, Explos., Pyrotech., 1987, 12, 46.
M. F. Gogulya, M. N. Makhov, A. Yu. Dolgoborodov, M. A. Brazhnikov, V. I. Arkhipov, V. G. Shchetinin, Combust., Explos. Shock Waves, 2004, 40, 44.
M. B. Talawar, R. Sivabalan, M. Anniyappan, G. M. Gore, S. N. Asthana, B. R. Gandhe, Combust., Explos. Shock Waves, 2007, 43, 62.
E. L. Metelkina, Russ. J. Org. Chem., 2007, 43, 1437.
V. A. Tartakovsky, A. S. Ermakov, V. A. Tartakovsky, T. S. Novikova, L. I. Khmel’nitskii, Russ. Chem. Bull., 1995, 44, 699.
Ch. Zhou, B. Wang, H. Huo, Q. Zhou, W. Yang, Z. Ye, Chin. J. Energ. Mater., 2014, 22, 576.
B. Wu, H. Yang, Y. Tang, Zh. Wang, Ch. Lu, G. Cheng, J. Energ. Mater., 2015, 33, 180.
E. L. Metelkina, T. A. Novikova, Russ. J. Org. Chem., 2002, 38, 1378.
E. L. Metelkina, Russ. J. Org. Chem., 2004, 40, 927.
E. L. Metelkina, T. A. Novikova, S. N. Berdonosova, D. Yu. Berdonosov, Russ. J. Org. Chem., 2005, 41, 440.
Zh. Feng, X. Guan, K. Xu, L. Jhai, F. Zhao, J. Mol. Struct., 2018, 1166, 369.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1318–1323, July, 2021.
The authors are grateful to the Program for the Development of Scientific Schools at the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences.
This paper does not contain descriptions of studies on animals or humans.
The authors declare no competing interests.
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Pokhvisneva, G.V., Ternikova, T.V., Luk’yanov, O.A. et al. Synthesis of high energy nitroguanidine derivatives. Russ Chem Bull 70, 1318–1323 (2021). https://doi.org/10.1007/s11172-021-3217-0
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DOI: https://doi.org/10.1007/s11172-021-3217-0