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Gold anode corrosion in an aqueous solution of 2,2-dimethyl-1,3-diaminopropane

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Abstract

The kinetics and mechanism of corrosion of an Au anode in a weakly basic aqueous solution of 2,2-dimethyl-1,3-diaminopropane (2,2-DM-1,3-DAP) were studied by gravimetry and cyclic voltammetry. Scanning and transmission electron microscopy was used to determine that under galvanostatic conditions the products of anode corrosion are reduced on a steel cathode with the formation of not only an electrolytic Au deposition on the cathode, but also colloidal gold nanoparticles in the electrolyte medium. The product of the interaction of 2,2-DM-1,3-DAP with atmospheric CO2, namely, the carbamic acid internal salt 3-ammonio-2,2-dimethyl-propylcarbamate, was isolated from the reaction solution.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    M. D. Vedenyapina, V. V. Kuznetzov, A. S. Dmitrenok, M. E. Minyaev, N. N. Makhova & M. M. Kazakova

Authors
  1. M. D. Vedenyapina
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  2. V. V. Kuznetzov
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  3. A. S. Dmitrenok
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  4. M. E. Minyaev
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  5. N. N. Makhova
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  6. M. M. Kazakova
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Corresponding author

Correspondence to M. D. Vedenyapina.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 735–744, April, 2021.

The authors are grateful to the Department of Structural Research of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences for carrying out electron microscopy of the samples.

This work was financially supported of the Science Schools Development Program of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences.

The authors declare no competing interest.

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Vedenyapina, M.D., Kuznetzov, V.V., Dmitrenok, A.S. et al. Gold anode corrosion in an aqueous solution of 2,2-dimethyl-1,3-diaminopropane. Russ Chem Bull 70, 735–744 (2021). https://doi.org/10.1007/s11172-021-3144-0

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  • DOI: https://doi.org/10.1007/s11172-021-3144-0

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