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Features of combustion of gas-generating solid compositions based on high-enthalpy dispersants

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Abstract

The features governing the high-rate thermal transformation (combustion without air access) of several dispersants (high-enthalpy N-heterocyclic compounds) were experimentally studied. The quantitative regularities of the combustion of both individual dispersants and their mixtures with isoprene rubber and ammonium perchlorate were examined. The dependences of consumption of individual dispersants on the nitrogen pressure, enthalpy of formation of the dispersants, and oxygen supply coefficient of the dispersant were determined. The dependences of the combustion rate on the contents of isoprene rubber and ammonium perchlorate were experimentally determined for the fuel compositions based on each dispersant. The results of the study can be used for the formation of optimal gas-generating fuel compositions.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. F. Zholudev, M. B. Kislov, I. S. Averkov, V. V. Raznoschikov, D. B. Lempert & L. S. Yanovskiy

  2. P. I. Baranov Central Institute of Aviation Motors, 2 ul. Aviamotornaya, 111116, Moscow, Russian Federation

    I. S. Averkov, V. V. Raznoschikov & L. S. Yanovskiy

  3. Special Design and Technology Bureau “Technolog,”, 33a prosp. Sovetskii, 192076, St. Petersburg, Russian Federation

    D. V. Dashko

  4. Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    L. S. Yanovskiy

Authors
  1. A. F. Zholudev
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  2. M. B. Kislov
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  3. I. S. Averkov
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  4. D. V. Dashko
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  5. V. V. Raznoschikov
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  6. D. B. Lempert
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  7. L. S. Yanovskiy
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Corresponding authors

Correspondence to I. S. Averkov, D. V. Dashko or D. B. Lempert.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 685–692, April, 2021.

This work was carried out in terms of state assignment (state registration No. AAAA-A19-119101690058-9).

This paper does not contain descriptions of studies on aminals or humans.

The authors declare no competing interests.

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Zholudev, A.F., Kislov, M.B., Averkov, I.S. et al. Features of combustion of gas-generating solid compositions based on high-enthalpy dispersants. Russ Chem Bull 70, 685–692 (2021). https://doi.org/10.1007/s11172-021-3137-z

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  • DOI: https://doi.org/10.1007/s11172-021-3137-z

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