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Rearrangements of polyaza(oxa-,thia-)heterocyclic carbanions in organic synthesis

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Russian Chemical Bulletin Aims and scope

Abstract

The present review is focused on the main transformation routes of sp2- and sp3-hybridized carbanions derived from the compounds containing two or more fused N,O,S-heterocycles. The rearrangement and fragmentation reactions and their applications in the synthesis of poorly available organic compounds are discussed. In the review, separate consideration is given to the reactions leading to a decrease, retention, and increase in the number of annulated heterocycles.

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  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    S. M. Ivanov

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 647–664, April, 2021.

This paper does not contain descriptions of studies on animals or humans.

The author declares no competing interests.

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Ivanov, S.M. Rearrangements of polyaza(oxa-,thia-)heterocyclic carbanions in organic synthesis. Russ Chem Bull 70, 647–664 (2021). https://doi.org/10.1007/s11172-021-3133-3

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