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Selective catalytic reduction of nitrogen oxides by ammonia over the dual-zone FeBeta∥MnCe/FeBeta catalyst

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Abstract

The properties of the FeBeta zeolite catalyst, MnCe/FeBeta composite catalyst, and FeBeta∥MnCe/FeBeta dual-zone catalytic system were studied in the selective catalytic reduction of nitrogen oxides with ammonia. The combination of the low-temperature (MnCe/FeBeta) and high-temperature (FeBeta) catalysts makes it possible to significantly improve the efficiency of NOx removal in a wide temperature range (200–500 °C) in the presence of the FeBeta∥MnCe/FeBeta system. It was found that this system also demonstrates high activity in the catalytic oxidation of residual ammonia retaining high selectivity in molecular nitrogen formation even under ammonia excess conditions (NH3: NO > 1).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47Leninsky prosp., 119991, Moscow, Russian Federation

    A. I. Mytareva, D. A. Bokarev, G. N. Baeva & A. Yu. Stakheev

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  1. A. I. Mytareva
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  2. D. A. Bokarev
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  3. G. N. Baeva
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  4. A. Yu. Stakheev
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Corresponding author

Correspondence to A. I. Mytareva.

Additional information

The authors are grateful to K. I. Maslakov (M. V. Lomonosov Moscow State University) for the XPS study of the samples.

Scientific Schools Development Program by N. D. Zelinsky Institute of Organic Chemistry (Russian Academy of Sciences) is gratefully acknowledged.

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Mytareva, A.I., Bokarev, D.A., Baeva, G.N. et al. Selective catalytic reduction of nitrogen oxides by ammonia over the dual-zone FeBeta∥MnCe/FeBeta catalyst. Russ Chem Bull 69, 2274–2280 (2020). https://doi.org/10.1007/s11172-020-3043-9

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  • DOI: https://doi.org/10.1007/s11172-020-3043-9

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