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Trifunctional thermosetting monomer with propargyl and phthalonitrile groups

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Russian Chemical Bulletin Aims and scope

Abstract

A new monomer containing thermosetting groups of two types, namely, propargyl ether and phthalonitrile, in the structure of the molecule was synthesized and studied. It was found that thermal polymerization was accompanied by the degradation of the monomer with propargyl ether decomposition. This problem can be solved using catalysts based on Cu(i) favoring the polymerization at both the propargyl group and phthalonitrile fragments. The cured monomer has a non-porous structure and high thermal properties (Vicat softening temperature 395 °C, T5% 451 °C). The low viscosity of the melt (<200 mPa s at 120 °C) and low glass-transition temperature (9 °C) of the monomer make it possible to use it for the formation of composite materials by vacuum infusion or injection into a mold.

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Authors and Affiliations

  1. Department of Materials Science, M. V. Lomonosov Moscow State University, Build. 73, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    M. V. Yakovlev

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    O. S. Morozov, E. S. Afanaseva, B. A. Bulgakov, A. V. Babkin, A. V. Kepman & V. V. Avdeev

Authors
  1. M. V. Yakovlev
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  2. O. S. Morozov
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  3. E. S. Afanaseva
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  4. B. A. Bulgakov
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  5. A. V. Babkin
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  6. A. V. Kepman
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  7. V. V. Avdeev
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Corresponding author

Correspondence to B. A. Bulgakov.

Additional information

This work was carried out in the framework of the state assignment of the Department of Chemistry of the M. V. Lomonosov Moscow State University (Agreement No. AAAA-A16-116053110012-5).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2183—2190, November, 2020.

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Yakovlev, M.V., Morozov, O.S., Afanaseva, E.S. et al. Trifunctional thermosetting monomer with propargyl and phthalonitrile groups. Russ Chem Bull 69, 2183–2190 (2020). https://doi.org/10.1007/s11172-020-3020-3

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  • DOI: https://doi.org/10.1007/s11172-020-3020-3

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