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Thermosetting matrices for composite materials based on allyl/propagryl substituted novolac resins

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Abstract

A new type of modified thermoset resins was synthesized by Williamson reaction from novolac resin and a mixture of allyl and propargyl chlorides of the different ratios with total allyl/propargyl substitution 50 %. The compositions of the resins were defined by nuclear magnetic resonance (1H NMR) spectroscopy, and the dependence of the cured material properties on the composition was established. An increase of a propargyl content resulted in char yield raise, and the maximum value had been found for propargylated resin which was 60 %. By differential scanning calorimetry (DSC) analysis of the curing process, it was demonstrated that exothermic enthalpy could be adjusted by varying the content of propargyl and allyl groups in the resin. It was shown that the resin substituted with allyl only ether could not be cured without decomposition, but an introduction of propargyl groups in allyl ether-modified resin allowed to obtain cured samples and thus to develop a new type of thermosetting resins.

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Notes

  1. Calculated with elementary unit Mr = 106

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Acknowledgments

The research was supported by the Ministry of Education and Science of the Russian Federation (work was performed as part of the contract between JSC RPA SPLAV and Lomonosov Moscow State University contract No. 02.G25.31.0169 “Development of technology for heat resistant and chemically resistant composites for pipeline parts”.

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Authors and Affiliations

  1. Division of Chemistry, Lomonosov Moscow State University, Moscow, Russia

    S. S. Nechausov, B. A. Bulgakov, A. V. Solopchenko, A. A. Serdan, D. I. Kalugin, A. V. Kepman & A. P Malakho

  2. Voronezh Aircraft Production Association, Voronezh, Russia

    A. Lyalin

Authors
  1. S. S. Nechausov
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  2. B. A. Bulgakov
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  3. A. V. Solopchenko
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  4. A. A. Serdan
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  5. D. I. Kalugin
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  6. A. Lyalin
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  7. A. V. Kepman
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  8. A. P Malakho
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Correspondence to S. S. Nechausov.

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Nechausov, S.S., Bulgakov, B.A., Solopchenko, A.V. et al. Thermosetting matrices for composite materials based on allyl/propagryl substituted novolac resins. J Polym Res 23, 114 (2016). https://doi.org/10.1007/s10965-016-1004-7

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  • DOI: https://doi.org/10.1007/s10965-016-1004-7

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