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Gold anode corrosion in aqueous solution of 1,2-diaminopropane with formation of colloidal gold nanoparticles

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Abstract

The kinetics and mechanism of corrosion of Au anode in a weakly basic aqueous solution of 1,2-diaminopropane were studied by gravimetry. According to transmission electron microscopy data, the products of anode corrosion under galvanostatic conditions are reduced on the steel cathode to give not only the electrolytic Au deposit on the cathode, but also colloidal gold nanoparticles in the electrolyte medium. A mixture of four gold complexes with 1,2-diaminopropane was isolated from the reaction solution; the ratio of the complexes and the structure of the predominant complex were proposed on the basis of NMR spectra.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    M. D. Vedenyapina, V. V. Kuznetsov, N. N. Makhova & D. I. Rodikova

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  1. M. D. Vedenyapina
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  2. V. V. Kuznetsov
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  3. N. N. Makhova
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  4. D. I. Rodikova
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Corresponding author

Correspondence to M. D. Vedenyapina.

Additional information

The authors are grateful to the Department of Structural Studies of the N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences. for electron microscopic examination of the samples.

Russian Chemical Bulletin, International Edition, Vol. 69, No. 10, pp. 1884–1891, October, 2020

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1884–1891, October, 2020.

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Vedenyapina, M.D., Kuznetsov, V.V., Makhova, N.N. et al. Gold anode corrosion in aqueous solution of 1,2-diaminopropane with formation of colloidal gold nanoparticles. Russ Chem Bull 69, 1884–1891 (2020). https://doi.org/10.1007/s11172-020-2974-5

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  • DOI: https://doi.org/10.1007/s11172-020-2974-5

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