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Controlled polymerization of styrene in the presence of Blatter’s radicals

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Abstract

Controlled polymerization of styrene (both self-initiated and initiated with azobisisobutyronitrile) in the presence of Blatter’s radical at 125 °C was studied. When using the radical initiator, there is no induction period. On the basis of UV spectroscopy and MALDI massspectrometry studies, it was established that the Blatter radical is completely consumed at the initial stage of the polymerization, inserting into almost all macromolecules. The prepared polystyrene exhibits the ability to reinitialization in post-polymerization and the synthesis of block copolymers.

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Authors and Affiliations

  1. National Research Lobachevsky State University of Nizhni Novgorod, 23 prosp. Gagarina, 603950, Nizhni Novgorod, Russian Federation

    Yu. L. Kuznetsova, A. S. Vavilova, Yu. B. Malysheva, I. D. Grishin, T. O. Burdyukova, E. A. Zaburdaeva, E. Yu. Polozov & A. Yu. Fedorov

  2. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 ul. Tropinina, 603137, Nizhni Novgorod, Russian Federation

    M. A. Lopatin

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  1. Yu. L. Kuznetsova
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  2. A. S. Vavilova
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  3. Yu. B. Malysheva
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  4. M. A. Lopatin
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  5. I. D. Grishin
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  6. T. O. Burdyukova
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  7. E. A. Zaburdaeva
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  8. E. Yu. Polozov
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  9. A. Yu. Fedorov
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Correspondence to Yu. L. Kuznetsova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1470–1477, August, 2020.

This work was performed under financial support of the Russian Foundation for Basic Research (Project No. 19-33-90090).

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Kuznetsova, Y.L., Vavilova, A.S., Malysheva, Y.B. et al. Controlled polymerization of styrene in the presence of Blatter’s radicals. Russ Chem Bull 69, 1470–1477 (2020). https://doi.org/10.1007/s11172-020-2925-1

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  • DOI: https://doi.org/10.1007/s11172-020-2925-1

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