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Effect of the [2-(diphenylphosphorylmethoxy)phenyl]diphenylphosphine oxide derivative structures on the extraction and ion-selective properties toward rare-earth elements

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Abstract

The effect of structures of the derivatives of [2-(diphenylphosphorylmethoxy)phenyl]-diphenylphosphine oxide (L1) on the complexation properties toward rare-earth elements (REE) was studied. A new structural analogue of L1, isopropyl 2-(diphenylphosphorylmethoxy)benzoate (L3), was synthesized. The extraction of REE by the carboxylated podand L3 in a 1,1,7-trihydrododecafluoroheptanol—water system with the HNO3 concentration varied in a range from 1 to 6 mol L−1 was studied. The stability constants of the neodymium(iii) and erbium(iii) nitrate complexes with L3 and 1-(methoxydiphenylphosphoryl)-2-diphenylphosphoryl-4-ethylbenzene (L2) and of lutetium(iii) nitrate and chloride complexes with L2 in 1,1,7-trihydrododecafluorheptanol were determined. The properties of the membranes of the ion-selective electrodes based on L1, L2, and L3 toward REE cations were tested. The crystal structures of L3 and [NdL3(NO3)3(DMSO)2] were determined by X-ray diffraction analysis.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    I. S. Ivanova, A. B. Ilyukhin & E. N. Pyatova

  2. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Building 4, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    S. V. Demin, G. S. Tsebrikova, V. P. Solov’ev, D. V. Baulin & A. Yu. Tsivadze

  3. M. V. Lomonosov Institute of Fine Chemical Technologies, MIREA — Russian Technological University, 78 prosp. Vernadskogo, 119454, Moscow, Russian Federation

    E. A. Zhogin

  4. Institute of Physiologically Active Compounds, Russian Academy of Sciences, 1 Severnyi proezd, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. E. Baulin

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  1. I. S. Ivanova
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  2. A. B. Ilyukhin
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  3. E. N. Pyatova
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  7. V. P. Solov’ev
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  8. D. V. Baulin
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  9. V. E. Baulin
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Correspondence to I. S. Ivanova.

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Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1336–1343, July, 2020.

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Ivanova, I.S., Ilyukhin, A.B., Pyatova, E.N. et al. Effect of the [2-(diphenylphosphorylmethoxy)phenyl]diphenylphosphine oxide derivative structures on the extraction and ion-selective properties toward rare-earth elements. Russ Chem Bull 69, 1336–1343 (2020). https://doi.org/10.1007/s11172-020-2907-3

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