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Extraction of Rare-Earth Elements(III) with Mixtures of 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone and Phosphoryl-Containing Podands

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Abstract

Extraction of rare-earth elements(III) ions from chloride solutions with mixtures of 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone and phosphoryl-containing podands in organic solvents has been studied. The observed significant synergistic effect is associated with the formation of hydrophobic mixed-ligand complexes of rare-earth elements(III). The stoichiometry of the extracted complexes has been determined, and the extraction constants have been calculated. The influence of the phosphoryl-containing podand structure, the organic solvent nature, and the aqueous phase composition on the efficiency of the extraction of rare-earth element(III) ions into the organic phase has been considered.

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Funding

This study was performed in the scope of the Governmental Task to Institute of Solid State Physics of the Russian Academy of Sciences, Institute of Problems of Microelectronics Technology and High-Purity Materials of the Russian Academy of Sciences, Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, and Institute of Physiologically Active Substances of the Russian Academy of Sciences. It was partially financially supported by the Russian Foundation for Basic Research (project no. 18-29-24069) and the Ministry of Education and Science of the Russian Federation in the scope of the Program for Improving Competitiveness of National University of Science and Technology “MISIS” among Leading Research Centers for 2013–2020 (no. K2-2016-070).

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Authors and Affiliations

  1. Institute of Solid State Physics of the Russian Academy of Sciences, ul. Akademika Osip’yana 2, Chernogolovka, 142432, Russia

    A. N. Turanov

  2. Institute of Problems of Microelectronics Technology and High-Purity Materials of the Russian Academy of Sciences, Chernogolovka, Russia

    V. K. Karandashev & V. A. Khvostikov

  3. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    V. E. Baulin & D. V. Baulin

  4. Institute of Physiologically Active Substances of the Russian Academy of Sciences, Chernogolovka, Russia

    V. E. Baulin

Authors
  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. V. E. Baulin
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  4. D. V. Baulin
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  5. V. A. Khvostikov
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Correspondence to A. N. Turanov.

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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 9, pp. 1431–1438.

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Turanov, A.N., Karandashev, V.K., Baulin, V.E. et al. Extraction of Rare-Earth Elements(III) with Mixtures of 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone and Phosphoryl-Containing Podands. Russ J Gen Chem 89, 1830–1835 (2019). https://doi.org/10.1134/S1070363219090172

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