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Formation of chitosan—surfactant complexes in aqueous-alcohol media

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Abstract

The complexation of chitosan and anionic surfactant, sodium dodecyl sulfate (DDS), in aqueous-alcohol media with a variable content of an organic cosolvent (methanol, ethanol, and propan-1-ol) was studied. A complicated effect of the composition of mixed solvents on the binding parameters of DDS by chitosan was observed. The introduction of 10–20 vol.% ethanol and propan-1-ol is accompanied by an increase in the degree of cooperative binding of DDS compared to that found in an aqueous solution, which leads to a decrease in the critical concentration of association and an increase in the cooperativity parameters.

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Authors and Affiliations

  1. Kazan National Research Technological University, 68 ul. Karla Marksa, 420015, Kazan, Russian Federation

    S. V. Shilova, A. Ya. Tret’yakova & V. P. Barabanov

Authors
  1. S. V. Shilova
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  2. A. Ya. Tret’yakova
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  3. V. P. Barabanov
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Corresponding author

Correspondence to S. V. Shilova.

Additional information

Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izyestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1316–1320, July, 2020.

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Shilova, S.V., Tret’yakova, A.Y. & Barabanov, V.P. Formation of chitosan—surfactant complexes in aqueous-alcohol media. Russ Chem Bull 69, 1316–1320 (2020). https://doi.org/10.1007/s11172-020-2904-6

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  • DOI: https://doi.org/10.1007/s11172-020-2904-6

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