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Association of chitosan in the presence of an anionic surfactant in aqueous-glycerol solutions

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The effect of additions of sodium tetradecyl sulfate as an anionic surfactant on the association of chitosan macromolecules in aqueous-glycerol solutions was studied by fluorescence probe spectroscopy and dynamic light scattering. Associates of 40–170 nm size are formed on reaching a certain critical concentration of chitosan in solutions. The critical association concentration of chitosan in solutions containing 10–30 vol % glycerol is higher than in aqueous solutions. Formation of chitosan–surfactant complexes enhances the tendency of chitosan macromolecules to association in water–glycerol mixed solvents.

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Authors and Affiliations

  1. Kazan National Research University of Technology, ul. Karla Marksa 68, Kazan, Tatarstan, 420015, Russia

    S. V. Shilova, A. Ya. Tret’yakova & V. P. Barabanov

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  1. S. V. Shilova
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  2. A. Ya. Tret’yakova
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  3. V. P. Barabanov
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Correspondence to S. V. Shilova.

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Original Russian Text © S.V. Shilova, A.Ya. Tret’yakova, V.P. Barabanov, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 8, pp. 1111−1118.

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Shilova, S.V., Tret’yakova, A.Y. & Barabanov, V.P. Association of chitosan in the presence of an anionic surfactant in aqueous-glycerol solutions. Russ J Appl Chem 90, 1372–1378 (2017). https://doi.org/10.1134/S1070427217080298

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  • DOI: https://doi.org/10.1134/S1070427217080298

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